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In: Chemistry

Magnesium hydroxide is only very slightly soluble in water. The reaction by which it goes into...

Magnesium hydroxide is only very slightly soluble in water. The reaction by which it goes into solution is:

Mg(OH)2(s) ⇌ Mg2+(aq) + 2 OH(aq)

What will happen if H+ is added to the solution and why?

Question options:

Solid dissolves. OH- concentration increases. Reaction moves to the left.

Solid dissolves. OH- concentration decreases. Reaction moves to the left.

Solid dissolves. OH- concentration increases. Reaction moves to the right.

Solid remains. OH- concentration increases. Reaction moves to the right.

Solid remains. OH- concentration increases. Reaction moves to the left.

Solid remains. OH- concentration decreases. Reaction moves to the right.

Solid dissolves. OH- concentration decreases. Reaction moves to the right.

Solid remains. OH- concentration decreases. Reaction moves to the left.

Solutions

Expert Solution

First, let us state the Le Chatelier principle which deals with changes in an equilibrium:

The statement is as follows:

If any equilibrium is disturbed, that is, change in conditions such as P,T, concentration, partial pressure, etc.., the system will counterbalance such change in order to favour the system's equilbirium.

  • Change in concentration
  • Change in pressure
  • Change in temperature

In this specifric case, we are only changing OH- concentration

since H+ addition will neutralize OH- as follows

OH- + H+ = H2O

therefore

Mg(OH)2(s) ⇌ Mg2+(aq) + 2 OH−(aq)

shifts toward Mg+2 and OH- prodution, since OH- is dissapearing

the solid will becomes MORE soluble

therefore,

solid dissolves; OH- decreases, since Mg+2 ions are taking up for hte neutralization and the shift moves toward the right


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