Question

In: Chemistry

Nitric acid and magnesium hydroxide react to form magnesium nitrate and water A) how many moles...

Nitric acid and magnesium hydroxide react to form magnesium nitrate and water

A) how many moles are in 83.1 ml of 1.581M nitric acid?

B) how many moles r in 54.3ml of 1.815M magnesium hydroxide?

C) what is the limiting reactant, and what is the theoretical yield of magnesium nitrate in gram?

D) if 2.831 g of mag. Nitrate r produced in the reaction what is the percent yield

Solutions

Expert Solution

(A) Given Molarity of HNO3(nitric acid) , M = 1.581 M

                                 Volume of HNO3 is , V = 83.1 mL = 0.0831 L

Number of moles of HNO3 is , n = Molarity x volume in L

                                                = 1.581 M x 0.0831 L

                                               = 0.131 moles

Therefore the number of moles of HNO3 is 0.131 mol

(B) Number of moles of Magnesium hydroxide,Mg(OH)2 is , n = Molarity x volume in L

                                               = 1.815 M x 0.0543 L

                                                 = 0.098 moles

Therefore the number of moles of Mg(OH)2 is 0.098 mol

(C) The balanced reaction when Nitric acid and magnesium hydroxide react to form magnesium nitrate and water is

2HNO3 + Mg(OH)2 Mg(NO3)2 + 2H2O

According to the balanced equation ,

2 moles of HNO3 reacts with 1 mole of Mg(OH)2

0.131 moles of HNO3 reacts with M mole of Mg(OH)2

M = ( 0.131x1) / 2

    = 0.065 moles

So 0.098 - 0.065 = 0.033 moles of Mg(OH)2 left unreacted so Mg(OH)2   is the excess reactant.

Since all the mass of HNO3 completly reacted , so HNO3 is the limiting reactant.

(D) From the balanced reaction ,

2 moles of HNO3 produces 1 mole of Mg(NO3)2

0.131 moles of HNO3 produces N mole of Mg(NO3)2

N = (0.131x1)/2

   = 0.0655 moles

Molar mass of Mg(NO3)2 = 24.3+2[(14+(3x16)]

                                     = 148.3 g/mol

So mass of Mg(NO3)2 produced is , m = molar mass xnumber of moles

                                                        = 148.3(g/mol) x 0.0655 mol

                                                        = 9.714 g    ----> which is the theoretical yield

& yield = ( actual yield/ theoretical yield) x100

          = ( 2.831/ 9.714)x100

         = 29.1 %


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