Questions
Calculate the pH of an aqueous solution of 0.225 M salicylic acid, which has a Ka...

Calculate the pH of an aqueous solution of 0.225 M salicylic acid, which has a Ka =1.0 x 10^-3

An explanation will be appreciated, a simple answer won't really help. Thank you!

In: Chemistry

Write equations for the reactions investigated. Label Sn1 or Sn2. 1)Butyl bromide in 15%NaI-acetone 2)Butyl bromide...

Write equations for the reactions investigated. Label Sn1 or Sn2.

1)Butyl bromide in 15%NaI-acetone

2)Butyl bromide in 1%ethanolic silver nitrate

?????3)Butyl chloride in 15% NaI-acetone

4) Butyl chloride in 1% ethanolic silver nitrate

5)Sec-butyl chloride in 15%NaI-acetone

6) Sec-butyl chloride in 1% ethanolic silver nitrate

7) Tert-butyl chloride in 15%NaI-acetone

8) Tert-butyl chloride in 1% ethanolic silver nitrate

9) Crotyl chloride in 15% NaI-acetone

10) Crotyl chloride in 1% ethanolic silver nitrate

Any help would be appreciated! I will rate your response in return!

In: Chemistry

Consider the titration of a 25.0 −mL sample of 0.180 M CH3NH2 with 0.155 M HBr....

Consider the titration of a 25.0 −mL sample of 0.180 M CH3NH2 with 0.155 M HBr. Determine each of the following.

A. initial pH

B. volume of added acid required to reach the equivalence point

C. pH at 6.0 mL of added acid

D. pH at one-half of the equivalence point

E. pH at the equivalence point

F. pH after adding 6.0 mL of acid beyond the equivalence point

In: Chemistry

What is the pH at the equivalence point when 25.00 mL of a 0.150 M solution...

What is the pH at the equivalence point when 25.00 mL of a 0.150 M solution of acetic acid (CH3COOH) is titrated with 0.10 M NaOH to its end point?

In: Chemistry

1. household vinegar is 5% of acetic acid. give the formula for acetic acid. show work...

1. household vinegar is 5% of acetic acid. give the formula for acetic acid. show work please!e

2. how could you distinguish solid barium chloride from solid barium sulfat?

do you think washing soda Na2CO3, could be used for the same purpose as baking soda NaHCO3? would Na2CO3 react with HCl ? write the chemocal equation. write the chemical equation for the reaction of NaHCO3 with HCl.

In: Chemistry

Post-Lab Questions Which data point can you obtain with greater accuracy from your graph-the pK values...

Post-Lab Questions

Which data point can you obtain with greater accuracy from your graph-the pK values from the "legs" or the isoelectric point from the point of inflection? Explain your answer.

In: Chemistry

t (s) [A] (M) ln[A] 1/[A] 0.00 0.500 −0.693 2.00 20.0 0.389 −0.944 2.57 40.0 0.303...

t
(s)
[A]
(M)
ln[A] 1/[A]
0.00 0.500 −0.693 2.00
20.0 0.389 −0.944 2.57
40.0 0.303 −1.19 3.30
60.0 0.236 −1.44 4.24
80.0 0.184 −1.69 5.43

Now that we know it os first order

What is the value of the rate constant for this reaction?

In: Chemistry

Q1, The total entropy change of a system and its surrounding is (a) in a(n) (b)...

Q1, The total entropy change of a system and its surrounding is (a) in a(n) (b) process.

  1. (a) larger than zero; (b) reversible
  2. (a) smaller than zero; (b) reversible
  3. (a) equal to zero; (b) reversible
  4. (a) equal to zero; (b) irreversible
  5. (a) smaller than zero; (b) irreversible

Q2, Standard enthalpy change (ΔH°) of a process involving gases is the enthalpy change of process at

  1. 1 atm and 298K.
  2. 1 atm and 273K.
  3. 273K.
  4. 1 atm.
  5. 298K.

Q3, The following values are noticed on the phase diagram of CO2: at its triple point:
T3 =216.8 K and P3 =5.11 atm; at its critical point: Tc =304.2 K and Pc =72.9 atm.

Which of the statements below about CO2 is correct?

  1. CO2 can exist as liquid at atmospheric pressure if it is brought to a temperature low enough.
  2. CO2 cannot exist in liquid phase at atmospheric pressure.
  1. CO2 cannot exist as solid if its temperature is higher than its triple point temperature T3.
  2. CO2 is said to be in supercritical condition if it is brought to a temperature higher than 304.2 K at atmospheric pressure
  3. CO2 cannot exist as vapour if its temperature is brought to lower than its triple point temperature 216.8K.

Q4, For a pure substance:

  1. its Gibbs energy always increases with the pressure at constant temperature.
  2. its Gibbs energy always increases with the temperature at constant pressure.
  3. its Gibbs energy always increases when the substance changes from solid to liquid or from liquid to vapour.
  4. its Gibbs energy always decreases when the substance changes from vapour to liquid or from liquid to solid.
  5. its Gibbs energy remains unchanged in a reversible phase change process.

In: Chemistry

MgSO4•7H2O is an example of hydrate, a substance that has fixed mass percent of water in...

MgSO4•7H2O is an example of hydrate, a substance that has fixed mass percent of water in the compound. Calculate the mass percent (%) composition of water in MgSO4•7H2O. (show your work.)

In: Chemistry

You are a studen in Organic Chemsitry lab and you are tasked with the job to...

You are a studen in Organic Chemsitry lab and you are tasked with the job to make 202 ppm solution of Rhodamine B (MM = 479.02 g/mol). How many moles of dye do you need to add to a 250 mL beaker of water to prepare this solution?

In: Chemistry

The automobile fuel called E85 consists of 85 % ethanol and 15 % gasoline. E85 can...

The automobile fuel called E85 consists of 85 % ethanol and 15 % gasoline. E85 can be used in so-called "flex-fuel" vehicles (FFVs), which can use gasoline, ethanol, or a mix as fuels. Assume that gasoline consists of a mixture of octanes (different isomers of C8H18), that the average heat of combustion of C8H18(l) is 5400 kJ/mol, and that gasoline has an average density of 0.70 g/mL. The density of ethanol is 0.79 g/mL.

For Part A, start with the given L of gasoline and use the density of the gasoline as well as the molar mass of  C8H18 to determine the moles of gasoline. Once you have found the moles of gasoline you will use the provided heat of combustion to determine the energy produced. You do not need to use Appendix C because you are using the provided heat of combustion.

For Part B, do the same with the ethanol. You will use the heat of combustion for ethanol from the extra credit homework problem 5.79. If you did not do the that homework problem, you will need to write the balanced equation for the combustion of ethanol paying attention to the phases. Use the phase of gas for the water. Then calculate the heat of the combustion reaction from the heats of formation in Table C.

For Part C, you will need to use a weighted average. This is the same formula we used to determine the average atomic mass.

For Part D, you are starting with the given gallons of gasoline and will need to use the heat of combustion produced for the given liters of gasoline as a conversion factor to determine the energy produced from the given gallons. The heat of combustion produced from the liters of gasoline is from Part A. Now take the energy produced from the gallons of gas and use that as the given. Using the heat of combustion produced for the liters of E85 from Part C, determine the gallons of E85 necessary to produce that much energy.

For Part E, you will use the gallons of gasoline

A)By using the information given as well as data in Appendix C, calculate the energy produced by combustion of 2.0 L of gasoline

B)By using the information given as well as data in Appendix C, compare the energy produced by combustion of 2.0 L of ethanol. Consider that water is in the gaseous state.

c)Assume that the density and heat of combustion of E85 can be obtained by using 85 % of the values for ethanol and 15 % of the values for gasoline. How much energy could be released by the combustion of 2.0 L of E85?

E)If gasoline costs $ 3.10 per gallon in the United States, what is the break-even price per gallon of E85 if the same amount of energy is to be delivered?

In: Chemistry

A solution containing 28.60 mg of an unknown protein per 29.0 mL solution was found to...

A solution containing 28.60 mg of an unknown protein per 29.0 mL solution was found to have an osmotic pressure of 3.80 torr at 15 ∘C. What is the molar mass of the protein?

Please show details on how to get to the answer:

Mmol = 4660 g/mol

In: Chemistry

Biochemistry 1. what is the biochemical cause for familial hypercholestemia? 2. What enzyme is targeted by...

Biochemistry

1. what is the biochemical cause for familial hypercholestemia?

2. What enzyme is targeted by the current cholesterol lowering drugs, the stains?

3. Under roles of lipoprotein and their interactions with the intestine, adipocytes liver and peripheral tissue.

4. The largest drugs to be approved as cholesterol lowering drugs are bind irreversibly to PSSCK9 protein. Find out what the role of PCSK9 is and why inhibitors of them would lower serum cholesterol level?

In: Chemistry

Question 1 2C2 H4 + 02 -- > 2C2 H40 Ethylene oxide is produced by the...

Question 1

2C2 H4 + 02 -- > 2C2 H40

Ethylene oxide is produced by the catalytic oxidation of ethylene. The feed into the reactor contains 1700 g/min ethylene and 3700 moles/min air.

a.      What is the limiting reactant?

b.      What is the extent of reaction if only 81% of the limiting reactant is converted to the product?

c.       What is the molar composition of the product stream?

Question 2

Air at 95 °F can hold maximum of 3.52 wt% water, defined as 100% humidity at 95°F. On a hot humid day the temperature is 95°F and the air contains 3.2 wt% water (90.9 % humidity). The air cooled to 68 °F because air at 68 °F can hold a maxium of 1.44 wt% water ( i.e 100% humidity at 68 °F), water condenses from the air. Hot humid air (95°F, 90.9% humidity) flows into a cooler at a rate of 154 .0 Kg/min. Calculate the flow rate of 2 streams leaving the cooler:

a.      Air at 68°F and 1OO% humidity (stream 1: air leaving the cooling unit)

b.      Water condensed from the air (stream 2: water leaving the cooling unit)

c.       What is the degree of freedom for the cooling unit

Question 3

A mixture of organic solvents containing 45.0 mole o/o xylene, 25.0o/o toluene, and the balance benzene (X) is fed to a distillation column. The bottom product contains 98.0 mole% xylene and no benzene, and 96.0°/o of the xylene in the feed is recovered in this stream. The overhead product is fed to a second distillation column. The overhead product from the second column contains 97.0o/o of the benzene in the feed to this column. The composition of this stream i 94.0 mole% benzene and the balance toulene.

a)      Draw and label a flow chart for the process

b)      Calculate the unknown process variables

c)      The percentage of the benzene in the process feed (i.e. the feed to the first column) that emerge ,in the overhead product from the second column.

d)      The percentage of toluene in the process feed that emerges in the bottom product from the second column.

If anybody can solve these questions I would rally appreciate it.

In: Chemistry

Discuss the fundamental principles, instrumentation, and analytical capabilities of thefollowing techniques: •Potentiometry •Cyclic voltammetry •Anodic Stripping...

Discuss the fundamental principles, instrumentation, and analytical capabilities of thefollowing techniques:

•Potentiometry

•Cyclic voltammetry

•Anodic Stripping voltammetry

(b) Which technique is most selective for the determination of Calcium? Explain.

(c) Using a typical example, discuss the mechanism of ionization used in mass spectrometry

In: Chemistry