In: Chemistry
1. Write the chemical equation for the reaction of an antacid containing magnesium hydroxide, Mg(OH)2, with stomach acid (hydrochloric acid, HCl) and then balance the equation.
2. If a tablet of the antacid neutralized 41.4 mL of 0.150 M hydrochloric acid then how many grams of magnesium hydroxide was in the tablet?
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3.Concentrated gastric acid is about 0.16 molar in concentration (0.16 M HCl), corresponding to a pH of 0.8. In the stomach, however, the solution becomes diluted to a pH between 1 and 2. Using the information from Q.5 calculate how many milliliters of gastric acid can be neutralized by 1 tablet of antacid?
(Show calculation)
The balanced reaction of Mg(OH)2 and HCl is
Mg(OH)2+2HCl -------->MgCl2+2H2O
molar masses : Mg(OH)2= 58 g/mole, HCl= 36.5 and MgCl2= 95 and H2O= 18
moles of HCl in 41.4ml of 0.15M= Molarity* Volume (L)=0.15*41.4/1000 =0.00621
The reaction suggets 2 moles of HCl requires 1 mole of Mg(OH)2 for complete neutralization
hence 0.00621moles of HCl requires 0.00621/2= 0.003105
Mass of Mg(OH)2= Moles* Molar mass of Mg(OH)2= 0.003105*58=0.18 gm
3. Basis :1 Liter of solution of molarity 0.16M. Moles of HCl =Molarity* Volume L=0.16
pH=-log [H+], when pH= 1, [H+]= 10-1=0.1 moles/L
since acid is diluted while moles of HCl remains at 0.16, Volume of solutopn = 0.16/0.1= 1.6L
A single dose of ant acid contains 250 mg of Mg(OH)2
Moles of Mg(OH)2= Mass/molar mass =250*10-3/ 58=0.0043 moles
From the reaction, moles of HCl required = 2*0.0043= 0.0086 moles
Volume of HCl required ( for a pH of 1)= 0.0086/0.1= 0.086 L = 86 ml
and volume of HCl required for a pH of 2= 0.0086/0.01 ( pH=2 means [H+] =10-2)= 0.86L= 860 ml