What is the Gibb's Standard Free Energy of Formation
ΔGf0? How may
ΔGreaction0 be used to...
What is the Gibb's Standard Free Energy of Formation
ΔGf0? How may
ΔGreaction0 be used to calculate the
equilibrium constant for a chemical reaction under standard
conditions?
Write a chemical equation for the formation reaction and then
calculate the standard free energy of formation of each of the
following compounds from the enthalpies of formation and the
standard molar entropies, using ∆G◦ r = ∆H◦ r - T∆S◦ r:
(a) NH3(g)
(b) H2O(g)
(c) CO(g)
(d) NO2(g)
What is the standard free energy of the reaction, in kJ, at 298K
for:
1 A (aq) + 1 B (aq) <--> 2 C (aq) + 2 D (aq)
if ΔH° (A)= -3.4134 kJ/mol , ΔH° (B) = 93.8823
kJ/mol, ΔH° (C) = -26.8495 kJ/mol, and ΔH° (D) = -39.4984
kJ/mol
ΔS° (A)= 33.3845 J/(mol K) , ΔS° (B) = 92.5722 J/(mol K) , ΔS°
(C) = -59.1781 J/(mol K) , and ΔS° (D) = -12.7602 J/(mol K)
What is the standard free energy change for the reaction below?
Is the reaction expected to be spontaneous under standard
conditions?
FeS(s) + O2(g) → Fe(s) + SO2(g)
Summarize why the difference between free energy change
and standard free energy change depends on the concentrations of
the reactants and products in biochemistry.
Explain the concept of free energy, discussing how it can be
used to determine whether a reaction is spontaneous or
non-spontaneous
Under which conditions would a reaction be spontaneous
regardless of temperature?
Under which conditions would a reaction be non-spontaneous
regardless of temperature?
I have a question about gibbs free energy vs gibbs standard free
energy.
We know that at equilibrium deltaG = 0 and Q = K, and deltaG
standard is a non-zero value.
But I don't understand. If I want to see if a reaction is at
equilibrium then I have to calculate the deltaG standard first,
before I can calculate deltaG to see if its value is 0 or not.
And everytime I do that, the deltaG standard equals 0...
1-1Based on the Gibbs free
energy of formation of substances listed in the table below,
calculate EMF for the following cells:
(i) Zn | Zn2+ (1.0 M) || H+ (1.0 M) |
O2 (1 atm) | Pt
(ii) Zn | Zn2+ (1.0 M) || Cu2+ (1.0 M) |
Cu
(iii) Pt | H2(g) (1 atm) | H+ (1.0 M) ||
H+ (1.0 M) | O2 (1 atm) | Pt
_______________________________________________
Substances
DGfo/ kJ mol-1
(298 K)
_______________________________________________
Zn2+(aq)
-147.0
ZnO(s) ...
Based on the standard free energies of formation, which of the
following reactions represent a feasible way to synthesize the
product?
A.
2C(s)+H2(g)→C2H2(g);
ΔG∘f=209.2 kJ/mol
B.
C(s)+O2(g)→CO2(g);
ΔG∘f=−394.4 kJ/mol
C.
2C(s)+2H2(g)→C2H4(g);
ΔG∘f=68.20 kJ/mol
D.
2CO(g)+O2(g)→2CO2(g);
ΔG∘f=−788.0 kJ/mol