In: Chemistry
Based on the standard free energies of formation, which of the following reactions represent a feasible way to synthesize the product?
A. | 2C(s)+H2(g)→C2H2(g); | ΔG∘f=209.2 kJ/mol |
B. | C(s)+O2(g)→CO2(g); | ΔG∘f=−394.4 kJ/mol |
C. | 2C(s)+2H2(g)→C2H4(g); | ΔG∘f=68.20 kJ/mol |
D. | 2CO(g)+O2(g)→2CO2(g); | ΔG∘f=−788.0 kJ/mol |
Solution:
As we know... if G
< 0 ...i.e. negative ....
the reaction would be...both spontaneous and correspondingly
feasible.....
And, if
G > 0 ....i.e.
positive
....the reaction wouldn't be ....neither spontaneous nor feasible...
Step - 1:
As we can see from the
above Table .....
G < 0 ....i.e.
negative for
both reaction(s)... 'B' .....and
'D'.....making both of them feasible reactions, and we have
the following....(given)
Gof
= -394.4 kJ/mol ...... for reaction
....'B'....
And...
Gof
= - 788.0 kJ/mol .... for reaction...
'D'...
Answer:
Therefore, based on the given and above shown data/informations, although both reaction 'B' and reaction 'D', represent a feasible way to synthesize the products .... the most feasible reaction should be.... reaction 'D'....... (i.e. the Answer)...
D.) 2CO (g) +
O2 (g) --------> 2 CO2 (g)...... (reaction
D)....Gof
= - 788.0 kJ/mol...... (Answer)