In: Chemistry
1. Determine the equilibrium constant for the following reaction at (3.950x10^2) K.
2 A(g) + B2(g) → 2 AB(s) ΔH° = -(2.2x10^2) kJ; ΔS° = -(3.988x10^2) J/K
2.
A+ (aq) + BC3- (aq) à A(BC3)(s) ΔH° f = -64.4 kJ/mol
For the above reaction ΔSsys is ________(positive or negative), and ΔG is __________ (positive or negative) and the reaction is _______________ (spontaneous or nonspontaneous) at 600K
3.
Which of the following pairs of reactants will result in a spontaneous reaction at 25°C. (select all that are spontaneous)
Pb2+(aq) + 2e- → Pb (s) Eºcell= -0.13V |
Cu+(aq) + e- → Cu (s) Eºcell= +0.52 |
Ag+(aq)+ e- → Ag (s) Eºcell= +0.80 |
Br2 (l)+ 2e- → 2 Br- (aq) Eºcell= +1.09 |
Li+(aq) + e- → Li (s) Eºcell= -3.04 |
Al 3+(aq)+ 3e- → Al (s) Eºcell= -1.66 |
Fe3+(aq) + 3e- → Fe (s) Eºcell= -0.036 |
Ni2+(aq) + 2e- → Ni (s) Eºcell= -0.23 |