Question

In: Chemistry

Boron is the fifth element in the periodic table. For the first ionization of boron, the...

Boron is the fifth element in the periodic table. For the first ionization of boron, the ionization energy is 0.8006 MJ/mol. Calculate the effective nuclear charge (Zeff) for the first ionization of boron.

Solutions

Expert Solution

Effective nuclear charge (Zeff) = sq.rt.(E.n^2/Rh)

Rh = 2.178 x 10^-21 kJ

E = 0.8006 MJ/mol = 800.6 kJ/mol

n = 2

we get Zeff for boron,

Zeff = sq.rt.(800.6 x 2^2/2.178 x 10^-21) = 1.21 x 10^12 mol-1


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