Question

In: Chemistry

Given the following thermochemical equations: X2+3Y2 equals 2XY3 and Delta H =-340 kJ X2+2 Z2 equals...

Given the following thermochemical equations:

X2+3Y2 equals 2XY3 and Delta H =-340 kJ

X2+2 Z2 equals 2XZ2 and Delta H = -170 kJ

2Y2 + Z2 equals 2Y2Z and Delta H=-260kJ

Calculate the change in enthalpy for the following reaction

4XY3+7 Z2 equals 6Y2Z+4XZ2

Solutions

Expert Solution

inverting equation #1..
2 XY3 -----> X2 + 3Y2... dH = +340 kJ.

and then multiplying by 2
4 XY3 ----> 2X2 + 6 Y2... dH = +680kJ =============>1

now you have 4 XY3 on the left.. as you need..

now you need to get rid of the 2 X2 on the right

2 x equation #2 will do that

2X2+4 Z2 -------> 4XZ2 and Delta H = -340 kJ=============>2

3 x equation #3

6Y2 +3Z2 ,------>6Y2Z and Delta H=-780kJ===========>3

--------------------------------------------------------------------------------------------------------------------------------------------------------

adding eqns

4 XY3 ----> 2X2 + 6Y2... dH = +680kJ ======>1

2X2+4 Z2 -------> 4XZ2 and Delta H = -340 kJ===>2

6Y2 +3Z2 ,------>6Y2Z and Delta H=-780kJ===>3

-----------------------------------------------------------------------------------------------

4 XY3 +7Z2 ----------->6Y2Z+ 4XZ2

--------------------------------------------------------------------------------------

+680-340-780

-440kJ


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