In: Chemistry
A)
Temperature change of ice -180C to 00C
T = 180C
q1 = mass of ice X specific heat of H2O(s) X T
= 60 X2.03 X 18
q1 = 2192.4 J = 2.1924 KJ
Phase change from ice to water
Heat of fusion of water = 6.01 KJ/mol
That mean to convert 1 mole of ice to water without change in temperature require heat 6.01 KJ/mol
1 mole of water = 18.01528 gm
To convert 18.01528 gm of ice to water without change in temperature require heat 6.01 KJ then to convert 60 gm of ice to water without change in temperature require heat 60 X6.01/18.01528 = 20.0163 KJ
q2 = 20.0163 KJ
Temperature change of water 00C to 250C
T = 250C
specific of water = 4.184 J/ g K
mass of water = 60 gm
q3 = mass of water Xspecific heat of H2O(l) X T
= 60 X 4.184 X 25
q3 = 6276 J = 6.276 KJ
total energy required = q1 + q2 + q3
= 2.1924 + 20.0163 + 6.276 = 28.4847 KJ
heat energy required to convert 60.0 g of ice at -18 degrees celcius to water at 25 degrees celcius = 28.4847 KJ
B) first calculate energy required to convert 1.50 mole water at 1000C to steam
Phase change from water to vapour
Heat of vaporization of water = 40.79 KJ/mol
That mean to convert 1 mole of water to 1 mole of vapour without change in temperature require heat 40.79 KJ/mol
then to convert 1.5 mole of water required heat = 1.5 X 40.79 = 61.185 KJ = 61185 J
Heat added at constant rate 24.0 j/s
then to add 61185 J heat required time = 61185 / 24 = 2549 second
it take for 1.50 mol of water at 100 degrees Celsius to be converted completely into steam if heat were added at a constant rate of 24.0 J/s = 2549 second = 42.48 minute