Question

In: Chemistry

How much heat is required to convert solid ice with a mass of 605 g and...

How much heat is required to convert solid ice with a mass of 605 g and at a temperature of -12.5 °C to liquid water at a temperature of 55.5 °C? (The specific heat of ice is cice = 2100 J/kgK, the specific heat of water is cwater = 4186.8 J/kgK, and the heat of fusion for water is: Lf = 334 kJ/kg.)

Solutions

Expert Solution

we have

mass of the ice, m = 605g = 0.605 kg

specific heat capacity of ice, cice = 2100 J / kg K

specific heat capacity of water, cwater = 4186.8 J / kg K

latent heat of fusion of ice, Lf (ice) = 334 kJ / kg

We can divide the entire process into three different process (just for calculation)

Q1 = heat required to convert ice at –12.5 °C to ice at 0 °C = m cice ΔT1

= 0.605 kg * 2100 J / kg K * {0 - (-12.5)} °C

= 15881.25 J

= 15.88 kJ

We are taking the difference between two temperatures in ΔT, therefore, the unit conversion from Celsius to Kelvin will not have any impact on magnitude. Obviously, the units will cancel out.

Q2 = heat required to melt ice at 0 °C to water at 0 °C = mLf (ice)

= 0.605 kg * 334 kJ / kg

= 202.07 kJ

Q3 = heat required to convert water at 0 °C to water at 55.5 °C = m cwater ΔT2

= 0.605 kg * 4186.8 J / kg K * (55.5 - 0) °C

= 140582.277 J

= 140.58 kJ

Q = Total heat required to convert ice at -12.5 °C to water at 55.5 °C = Q1 + Q2 + Q3

= (15.88 + 202.07 + 140.58) kJ

= 358.53 kJ


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