A water is in equilibrium with CO2 in the atmosphere (partial
pressure is 3.16 .10‾⁴atm) and with CaCO3(s). The pH is 8.1.
Ignoring Ca complexes, what is the
solubility (S) of Ca?
What is the pH at 25 ∘C of water saturated with CO2 at a partial
pressure of 1.20 atm ? The Henry's law constant for CO2 at 25 ∘C is
3.1×10−2mol/L-atm. The CO2 is an acidic oxide, reacting with H2O to
form H2CO3.
Calculate the cell voltage for the
following reaction at 25o C:
2 Cr3+ (aqueous; 0.010 M) + H2 (gas at 1
atm)
è 2 Cr2+ (aqueous; 0.050 M) + 2H+ (aqueous;
pH = 2.50)
The Eo for the reaction Cr3+ (aq) +
e- ==è Cr2+ (aq) is - 0.40 V vs. the standard
hydrogen half-cell.
Consider the reaction shown below.
PbCO3(s) PbO(s) + CO2(g)
Calculate the equilibrium pressure of CO2 in the system at the
following temperatures.
(a) 210°C atm = _______ atm
(b) 480°C atm = _______ atm
Note: To find the value of the
equilibrium constant at each temperature you must first find the
value of G0 at each temperature by using the equation G0 = H0 -
TS0. For this reaction the values are H0 = +88.3 kJ/mol and S0=
151.3 J/mol*K
Consider the decomposition of barium carbonate:
BaCO3(s)???BaO(s)+CO2(g)
A) Calculate the equilibrium pressure of CO2 at 298 K.
B) Calculate the equilibrium pressure of CO2 at 1300K .
The water in a lake has a pH of 6. The water is in equilibrium
with atmospheric carbon dioxide which has a pressure of
PCO2= 10-3.5.
What is the concentration of the carbonate ion
(CO32-) in the water?
The Henrys Constant for carbon dioxide is KH = 10-1.5
atm•L/mol
Other Info:
R= 0.08206 atm•L/mole•K = 1.987 cal/mole•K = 8.314 J/mole•K
1 Joule = Newton • Meter
1 atm = 1.013 X 105 N/m2 = 1.013 X
105 Pa
1 gallon...
*** ONLY NEED C
Calculate the pH for each of the following cases in the
titration of 50.0 mL of 0.250 M HClO(aq) with 0.250 M KOH(aq). The
ionization constant for HClO can be found here.
(a) before addition of any KOH
(b) after addition of 25.0 mL of KOH (
c) after addition of 40.0 mL of KOH (
d) after addition of 50.0 mL of KOH (
e) after addition of 60.0 mL of KOH