Question

In: Chemistry

Using the equation below answer the following: dq = (3nR/2)dT + (nRT/V)dV a. Write the abstract...

Using the equation below answer the following:

dq = (3nR/2)dT + (nRT/V)dV

a. Write the abstract form of this total differential.

b. The way it is written, q is a function of ____ and ______.

c. Detetermine whether the differential is exact.

d. Determine whether q is a state function.

Solutions

Expert Solution

a) The abstract differential is written as

q = Aq + B

where q is the differential function and A is the value of the function while B is a constant.

b) The partial differential shows that dq depends on both dT and dV; therefore, q is a function of the temperature, T and volume, V of the system under study.

c) q depends on both T and V. q is a path function, i.e, depends on the path taken by the system. A path function is always an exact differential; hence, q is an exact differential.

d) q is path function, i.e, depends only on the path taken by the system. q can have different values depending on the different paths taken by the system. q doesn’t depend on the state of the system; hence, q is not a state function.


Related Solutions

A. Show that the ideal gases following PV=nRT satisfy (dp/dv)(dv/dt)(dt/dp)=-1. B. Show that van see waals...
A. Show that the ideal gases following PV=nRT satisfy (dp/dv)(dv/dt)(dt/dp)=-1. B. Show that van see waals fluids following P=(RT/V-b) - a/V^2 satisfy (dp/dv)(dv/dt)(dt/dp)=-1. C. Use the fundamental relation, dH=TdS + VdP and Maxwell equations to show that (dH^ig/dV) = 0, which means that enthrall of ideal gases us independent of volume.
Show that dg = -sdT + vdp is equivalent to dg = v(dp/dv)dv + (v(dp/dt)-s)dt gibbs...
Show that dg = -sdT + vdp is equivalent to dg = v(dp/dv)dv + (v(dp/dt)-s)dt gibbs energy equation
For Van Der Waals equation (P + a/V2)(V - b) = nRT How can you find...
For Van Der Waals equation (P + a/V2)(V - b) = nRT How can you find the values of "a" and "b" using an experiment? Please explain the method of the experiment too
Solve using the same approach as the solution using Matlab for this differential equation d^2y/dt^2 +...
Solve using the same approach as the solution using Matlab for this differential equation d^2y/dt^2 + 6dy/dt + 9y = cos(t) has initial conditions y(0)=1 y'(0)=2, Find Y(s) and without finding y(t), determine what function of time will appear in the solution %} clear, clc syms Y s t real rhs = laplace(cos(t),t,s) eqn1 = s^2*Y - s*2 - 1 + 6*s*Y -1 + 9*Y ==rhs myanss = solve(eqn1,Y) mypart = partfrac(myanss,'FactorMode','real') %{ mypart = (0.08*s + 0.06)/(s^2 + 1.0)...
1. Consider the following second-order differential equation. d^2x/dt^2 + 3 dx/dt + 2x − x^2 =...
1. Consider the following second-order differential equation. d^2x/dt^2 + 3 dx/dt + 2x − x^2 = 0 (a) Convert the equation into a first-order system in terms of x and v, where v = dx/dt. (b) Find all of the equilibrium points of the first-order system. (c) Make an accurate sketch of the direction field of the first-order system. (d) Make an accurate sketch of the phase portrait of the first-order system. (e) Briefly describe the behavior of the first-order...
Write dt/ds with constant H in terms of T,P,V.
Write dt/ds with constant H in terms of T,P,V.
Answer the below questions using 200-250 words for each answer. DQ 1: Assessing healthy behavior choices...
Answer the below questions using 200-250 words for each answer. DQ 1: Assessing healthy behavior choices These don’t need to be answered in 1-2-3 order. Use the following questions as a guide for your answer. They are the springboard for discussion and the topics should be addressed in your answer. Be sure to support your opinions and suggestions. That is what academic discussion is all about!: Have you personally used exercise to manage stress? In what situations and with what...
23. Consider a 2D spacetime whose metric is: ds^2 = −dt^2 + [f(q)]^2 dq^2 (3) where...
23. Consider a 2D spacetime whose metric is: ds^2 = −dt^2 + [f(q)]^2 dq^2 (3) where f(q) is any function of the spatial coordinate q. a) Show that the t component of the geodesic equation implies that dt dτ is contant for a geodesic. b) The q component of the geodesic equation is hard to integrate, but show that requiring u · u = −1 implies that f dq dτ is a constant for a geodesic. c) Argue then that...
You are required to write an abstract and title using the below information. Submission requirements: -...
You are required to write an abstract and title using the below information. Submission requirements: - Word length: 300 words (strictly enforced) - -Information - A number of case studies using data about disasters that had significant economic consequences were undertaken by the researchers, and these studies looked at the investment advice provided by the Home Budget Management System and whether it actually proved to be accurate. - In this paper a new Domestic Budget Management System called the Home...
what is the code to solve and graph the following function in matlab dv/dt=80.5(1-e^(.4t))
what is the code to solve and graph the following function in matlab dv/dt=80.5(1-e^(.4t))
ADVERTISEMENT
ADVERTISEMENT
ADVERTISEMENT