Question

In: Chemistry

We are starting on equilibrium constant & the Le Chaleiter Principle. Can you please explain how...

We are starting on equilibrium constant & the Le Chaleiter Principle. Can you please explain how to work these problems, so that I can better understand, and be able to answer the remainder of the questions going forward?

Fe3+ + SCN-  FeSCN2+

(colorless) (red)

Naming: iron(III) ion (Fe3+); thiocyanate anion (SCN1-); ferrithiocyanate (FeSCN2+), a red complex cation.

Part 1: When Fe(NO3)3 was added to the system,

  • Write the equilibrium constant, Kc .
  • Which ion in the equilibrium system caused the "stress"?
  • Which way did the equilibrium shift?
  • What happened to the concentration of SCN-?
  • What happened to the concentration of FeSCN2+?

Part 2: When NaSCN was added to the system,

  • Which ion in the equilibrium system caused the "stress"?
  • Which way did the equilibrium shift?
  • What happened to the concentration of Fe3+?
  • What happened to the concentration of FeSCN2+?

Part 3: When AgNO3 was added to the system, it caused the precipitation of solid AgSCN.

  • Which ion in the equilibrium had its concentration changed by addition of AgNO3?
  • Did the concentration of that ion increase or decrease?
  • When AgNO3 was added, which way did the equilibrium shift?

What happen to the color of the solution?

Solutions

Expert Solution

Note: left to right side shift of equilibrium = forward direction shift of equilibrium

right to left side shift of equilibrium = backward direction or reverse direction shift of equilibrium

Let me know if you have any queries regarding this.


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