In: Chemistry
1. A 100-watt lightbulb radiates energy at a rate of 100 J/s
(The watt, a unit of power, or energy over time, is defined as 1
J/s). If all of the light emitted has a wavelength of 505nm, how
many photons are emitted per second? (Assume three significant
figures in this calculation.)
2.Calculate the de Broglie wavelength of a 143-g baseball traveling
at 80 mph .
3.An electron undergoes a transition from an initial (ni) to a final (nf ) energy state. The energies of the ni and nf energy states are −2.179×10−18 J and −8.720×10−20 J, respectively.
Calculate the wavelength (λ) of the light in nanometers (nm) corresponding to the energy change (ΔE) value of this transition. You can use the following values for your calculations:
Planck′s constant (h)speed of light (c)1 m===6.626×10−34 J⋅s2.998×108 m/s109 nm
Q. 1)
Power = 100 w (J/s)
Wavelength of a photon = 505 nm = 505 E -9 m
Calculation of energy of a photon
E = hc/l = sf
Here E is energy in J , h is planks constant = 6.626 E-34 ,
c = speed of light = 3.0 E8 m/s
l = is wavelength in m
E = 6.626 E-34 Js x 3.0 E8 m/s )/ 505 E-9 m
= 3.94 E-19 J
Calculation of number of photon
Emission of energy per s = 100 J
Number of photon in 100 J = 100 J x 1 photon / 3.94 E-19 J
= 2.54 E20 photon
Since the energy emission is for one second so photon emitted per second
= 2.54 E20 photon
Q. 2 )
l = h/P
Here l = is wavelength in m , h is planks constant
P : momentum = mv
Here m is mass in kg and v is velocity in m/s
Calculation of mass in kg
= 143 g x 1 kg / 1000 g
= 0.143 kg
V = 80 m/hr
Conversion of velocity to m/s
= (80 m/ hr )x (1hr/3600 s)
= 0.022 m/s
l = 6.626 E-34 J per s / (0.143 kg x 0.0222 m/s)
= 2.085 E-31 m
3.
l = hc / Delta E
Delt a E = E(final) – E(initial)
l = 6.626 E-34 Js x 2.998 E8 m per s )/ [ ( -8.720 E-20 J ) – (- 2.179 E-18 ) ]
= 9.50 E-8 m
l = 9.50 E-8 m