Question

In: Chemistry

Assume that you have a cylinder fitted with a movable piston and enclosing a fixed amount...

Assume that you have a cylinder fitted with a movable piston and enclosing a fixed amount of gas. Provide a mathematical proof to your answer for each of the following cases.
​A. What would happen to the gas pressure inside the cylinder if you decrease the volume to one-fourth the original volume while holding the temperature constant?
​B. What would happen to to the gas volume inside the cylinder if the pressure is doubled and the Kelvin temperature is doubled?

Solutions

Expert Solution

Since there is fixed amount of gas , the number of moles of gas are constant .

Now using the ideal gas law , pV = nRT , where p is pressure , V is volume , n is number of moles , R is universal gas constant and T is temperature

A)

p1 xV1 = p2x V2

Now V2 = V1/4

So ,

p1 xV1 = p2 xV1 /4

p2 = 4 p1

So the gas pressure increases four folds ( quadruples ) when the volume was decreased to one fourth.

B)

p1 xV1x T2 = p2 xV2x T1

Now , p2 = 2p1 and T2 = 2T1

So ,

p1 x V1 x 2T1 = 2p1 x V2 x T1

V1 = V2

So there will be no change in the volume of gas , when pressure and temperature is doubled , it remains same .


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