In: Chemistry
Use data from the table below to calculate the equilibrium constants at 25 ∘C for each reaction.
Standard Thermodynamic Quantities for Selected Substances
at 25∘C
Substance | ΔH∘f(kJ/mol) | ΔG∘f(kJ/mol) | S∘(J/mol⋅K) |
H2(g) | 0 | 0 | 130.7 |
N2(g) | 0 | 0 | 191.6 |
Br2(g) | 30.9 | 3.1 | 245.5 |
Cl2(g) | 0 | 0 | 223.1 |
NO2(g) | 33.2 | 51.3 | 240.1 |
N2O4(g) | 9.16 | 99.8 | 304.4 |
NH3(g) | -45.9 | -16.4 | 192.8 |
P4(g) | 58.9 | 24.4 | 280.0 |
PH3(g) | 5.4 | 13.5 | 210.2 |
Part A
2NO2(g)⇌N2O4(g)
Find K
Part B
Br2(g)+Cl2(g)⇌2BrCl(g)
ΔG∘f for BrCl(g) is -1.0 kJ/mol
Find K