Question

In: Chemistry

What is the standard voltage or cell potential of a Cr-Hg cell? (Remember to switch one-half...

What is the standard voltage or cell potential of a Cr-Hg cell? (Remember to switch one-half reaction to oxidation and to balance the number of electrons--use paper.)

Cr3+(aq)+ 3e- → Cr(s) Eo = -0.74 V
Hg2+(aq)+ 2e- → Hg(l) Eo = +0.789 V

Solutions

Expert Solution

Cr3+(aq)+ 3e- → Cr(s)    Eo = -0.74 V
Hg2+(aq)+ 2e- → Hg(l)           Eo = +0.789 V

2Cr(s) --------------------> 2Cr^3+ + 6e^-      E0 = 0.74v         oxidation

3Hg^2+ + 6e^- -------> 3Hg(l)                   E0 = 0.789v    reduction

-----------------------------------------------------------------------------

2Cr(s) + 3Hg^2+(aq) ------------> 2Cr^3+(aq) + Hg(l)        E0 cell = 1.529v


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