Question

In: Chemistry

Estimate the temperature knowing the following reaction is spontaneous: CH₄(g) + N₂(g) → HCN(g) + NH₃(g)...

Estimate the temperature knowing the following reaction is spontaneous: CH₄(g) + N₂(g) → HCN(g) + NH₃(g)   ΔH° = +163.8kJ, ΔS° = +16.1 J/K

Solutions

Expert Solution

Apply Free energy equation

dG = dH - T*dS

if dG < 0, this will be spontaneous

then

dG = 163.8 - T*(16.1/1000)

and we know this must be less than 0

163.8 - T*(16.1/1000) < 0

163.8 < 0.0161*T

163.8/0.0161 < T

10173.91 < T

that is,

T > 10173 K

T must be pretty high in order to occurs this at STP


Related Solutions

What is the lowest temperature at which the following reaction is spontaneous? H2O(g) + C(graphite) ---->...
What is the lowest temperature at which the following reaction is spontaneous? H2O(g) + C(graphite) ----> H2(g) + CO(g)
Determine whether or not the following gas phase reaction is spontaneous at 25 degrees Celsius. CH4(g)+N2(g)=HCN(g)+NH3(g)
Determine whether or not the following gas phase reaction is spontaneous at 25 degrees Celsius. CH4(g)+N2(g)=HCN(g)+NH3(g)
Estimate ΔG°rxn for the following reaction at 407 K. HCN(g) + 2 H2(g) → CH3NH2(g) ΔH°=...
Estimate ΔG°rxn for the following reaction at 407 K. HCN(g) + 2 H2(g) → CH3NH2(g) ΔH°= -158.0 kJ; ΔS°= -219.9 J/K answer choices -68.5 kJ +247 kJ -247 kJ +68.5 kJ +61.9 kJ
What is ΔG° at 298 K for the following reaction? HCN( g )+N H 3 (...
What is ΔG° at 298 K for the following reaction? HCN( g )+N H 3 ( g )→C H 4 ( g )+ N 2 ( g ) ;   ΔH°=−164.1kJ;    ΔS°=−17J/K   at   298 K?
a) Is the following reaction spontaneous at standard reaction conditions? b) At what temperature (oC) does...
a) Is the following reaction spontaneous at standard reaction conditions? b) At what temperature (oC) does the reaction become spontaneous? CaCO3(s) --> CaO(s) + CO2(g)
Estimate delta Grxn for the following reaction at 427K. HCN(g)+2H2------->CH3NH2(g) delta H= -158.0Kj delta S= -219.9...
Estimate delta Grxn for the following reaction at 427K. HCN(g)+2H2------->CH3NH2(g) delta H= -158.0Kj delta S= -219.9 j/k +64.1kJ -64.1kJ -252kJ +61.9KJ +252Kj
For the following questions, consider the following reaction at a certain temperature: S2Cl2(g)+Cl2(g)⇌2SCl2(g) The reaction was...
For the following questions, consider the following reaction at a certain temperature: S2Cl2(g)+Cl2(g)⇌2SCl2(g) The reaction was allowed to establish equilibrium and then the equilibrium concentrations of reactants and products in the reaction mixture were measured, and recorded in the table below. (Even though this a gaseous reaction, instead of recording pressures, the concentrations of the gases were measured in molarity, making this a Kc problem. S2Cl2(g)0.050 MCl2(g)0.050 MSCl2(g)0.100 M Part G Because the concentrations provided above are equilibrium concentrations, plug...
Consider the following reaction: H2(g) + I2(g) ⇌ 2HI(g) At a particular temperature, a reaction mixture...
Consider the following reaction: H2(g) + I2(g) ⇌ 2HI(g) At a particular temperature, a reaction mixture at equilibrium contains pressures of H2 = 0.958 atm, I2 = 0.877 atm, and HI = 0.020 atm. At the same temperature, a second reaction mixture (not at equilibrium) contains pressures of H2 = 0.621 atm, I2 = 0.621 atm, and HI = 0.101 atm. What will be the partial pressure of HI when the second reaction mixture reaches equilibrium? a) 0.0144 atm b)...
Determine the equilibrium constant for the following reaction at 655 K. HCN(g) + 2 H2(g) →...
Determine the equilibrium constant for the following reaction at 655 K. HCN(g) + 2 H2(g) → CH3NH2(g) ΔH° = -158 kJ; ΔS°= -219.9 J/K. Determine the equilibrium constant for the following reaction at 655 K. HCN(g) + 2 H2(g) → CH3NH2(g) ΔH° = -158 kJ; ΔS°= -219.9 J/K A. 3.07 × 1011 B.13.0 C. 3.26 × 10-12 D. 3.99 × 1012 E. 2.51 × 10-13
Determine the equilibrium constant for the following reaction at 655 K. HCN(g) + 2 H2(g) ?...
Determine the equilibrium constant for the following reaction at 655 K. HCN(g) + 2 H2(g) ? CH3NH2(g); ?H
ADVERTISEMENT
ADVERTISEMENT
ADVERTISEMENT