I'm confused on how bonding works with metalloids. Will it be an ionic or covalent bond? For example P and As
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Sketch the appearance of the 1 H-NMR spectrum of diethyl ether using J = 6.97 Hz and the data in Q2 in a spectrometer operating at (a) 350 MHz, (b) 650 MHz.
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Consider the reaction shown. Suppose Meredith started with 0.51 g of sodium bromide, and 0.46 mL of 2,3-dimethylbutane for her reaction. Assuming the 2,3-dimethylbutane is the limiting reactant, how many grams, in theory, of 2,3-dibromo-2,3-dimethylbutane can be formed in the reaction?
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Q2: When 500.0 mL of 2.00 M Ba(NO3)2 solution at 25.0 °C is mixed with 500.0 mL of 2.00 M Na2SO4 solution at 22.0°C in a coffee-cup calorimeter, the white solid BaSO4 forms, and the temperature increases to 28.2°C. Assume that the calorimeter is insulated and has negligible heat capacity, the specific heat capacity of the solution is 4.184 J/g°C, and the density of the final solution is 1.0 g/mL. Answer the questions below using the Balanced Equation: Ba(NO3)2 (aq)+ Na2SO4 > BaSO4 (s) + 2NaNO3 (aq). Answer to correct amount of Significant Figures
Determine the heat of the reaction in J
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Determine the pH of an aqueous solution of Fe(CN)63-, prepared using FeCl3 and NaCN with formal concentrations of 0.001832 M and 0.5120 M.
logKf(Fe(CN)63-) = 43.6 Ka(HCN) = 6.2x10-10
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Balance these equations for reactions occurring in a basic solution. Don't include physical states for your answer.
CrO2- + S2O82- → CrO42- + SO42-
Au + CN- + O2 → Au(CN)4- + OH-
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Calculate the pH of the solution after the addition of the following amounts of 0.0536 M HNO3 to a 60.0 mL solution of 0.0750 M aziridine. The pKa of aziridinium is 8.04.
a) 0.00 mL of HNO3; Ph=
b)8.28mL of HNO3; Ph=
c) 42.0ml of HNO3
d) 84.0 mL of HNO3; Ph=
f) 88.5 mL of HNO3; Ph=
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A mixture is prepared using 27.00 mL of a 0.0774 M weak base (pKa = 4.635), 27.00 mL of a 0.0581 M weak acid (pKa = 3.189) and 1.00 mL of 0.000116 M HIn and then diluting to 100.0 mL, where HIn is the protonated indicator. The absorbance measured at 550 nm in a 5.000 cm cell was 0.1123. The molar absorptivity (ε) values for HIn and its deprotonated form In– at 550 nm are 2.26 × 104 M–1cm–1 and 1.53 × 104 M–1cm–1, respectively. 1.) What is the pH of the solution? 2.)What are the concentrations of In– and HIn? respectively 3.)What is the pKa for HIn?
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Instructions: For each part...Calculate the theoretical yield and percent yield. Then calculate the overall yield.
I am really struggling with this and have been working on it for awhile. Could you please show a step by step for my understanding?
Cyclohexanol: molecular weight 100.16g/mol
Cyclohexanol: density 0.947 g/cm 3
Part A: dehydration of cyclohexanol
Amount of cyclohexanol used (g): 7.4 g
Amount of cyclohexanol obtained (g): 1.611g
Cyclohexene: molecular weight 82.14 g/mol
Cyclohexene: density 0.81 g/cm 3
Part B: Oxidative Cleavage of Cyclohexene
Amount of cyclohexene used (g): 1.34 g
Mass of crude adipic acid (g): .394g
Mass of recrystallized adipic acid (g): 0.036g
Recrystallization percent recovery: 9.14%
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Trichloroethene (TCE) is a common groundwater contaminant. In terms of cancer risk, which would be better:
(1) to drink un-chlorinated groundwater groundwater with 10 ppb TCE, or (2) drink surface that, as a result of chlorination, contains 50 ppb chloroform. Assume a 30-year consumption period. The potency factor for TCE is 1.1×10^-2 (mg/kg day)^-1 and the potency factor for chloroform is 6.1×10^-3 (mg/kg day)^-1.
(Risk for TCE = 1.35×10-6)
I know the risk equation is: (Potency Factor)( CDI) but I wasn't sure what volume to use for the calculation since it isnt given
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In the distillation apparatus, it is important that the bulb of the thermometer is placed below the sidearm of the still head. Briefly explain why the thermometer placement is so important.
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Phosphorus pentachloride decomposes at higher temperatures.
PCl5(g) ⇄ PCl3(g) + Cl2(g)
An equilibrium mixture at some temperature consists of
3.03 g PCl5, 208.23 g/mol
4.86 g PCl3, 137.33 g/mol
3.59 g Cl2, 70.91 g/mol
in a 1.00-L flask.
If you add 1.31 g of Cl2, how will the equilibrium be affected and what will the concentration of PCl5 be when equilibrium is reestablished?
shift left
shift right
no shift will occur
[PCl5] = mol/L
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When the following skeletal equation is balanced under basic conditions, what are the coefficients of the species shown? SiO32- + Br- --> Br2 + Si Water appears in the balanced equation as a (reactant, product, neither) with a coefficient of . (Enter 0 for neither.) Which species is the reducing agent?
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When the following equation is balanced properly under acidic conditions, what are the coefficients of the species shown? Ag+ + Mg-->Ag + Mg2+ Water appears in the balanced equation as a (reactant, product, neither) with a coefficient of . (Enter 0 for neither.) How many electrons are transferred in this reaction?
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