1) Generate a titration curve (pH vs. mL NaOH) for the titration
of 10 mL 0.15M HCl with 0.15M NaOH ( suggest 2mL intervals up to 16
mL).
Calculations:
mL NaOH
pH
0
2
4
6
8
10
12
14
16
2) Make another titration curve using acetic acid instead of HCl
(same concentration)
Sketch a titration curve for 50 mL of 0.10 M HCl titrated with
0.15 M NaOH.
Include on the graph:
a) The initial pH
b) The volume of the equivalence point
c) The pH at the equivalence point
d) The pH after addition of 50 mL of NaOH
SHOW STEPS
Titration of 50.0mL of 0.100M HX (Ka=1.5x10^-5) with 0.100M
NaOH. Calculate the pH of:
- buffer formed at the addition of 12.5mL NaOH
- buffer formed at the addition of 25.0mL NaOH
- buffer formed at the addition of 37.5mL NaOH
- solution obtained at the endpoint
Please do the endpoint especially!
Draw the titration curve (pH versus mL of NaOH added) that would
be obtained from the titration of 30 mL of a 0.10 M solution of an
unknown triprotic acid, H3A (Ka1 = 1.26 x 10–3; Ka2 = 5.6 x 10–6;
Ka3 = 3.32 x 10–10) with 0.10 M NaOH. Indicate the volume needed to
reach the first, second, and third equivalence points and the pH at
the half equivalence points for the three titration regions.
Question 3: Draw the titration curve (pH versus mL of NaOH
added) that would be obtained from the titration of 30 mL of a 0.10
M solution of an unknown triprotic acid, H3A (Ka1 = 1.26 x 10–3;
Ka2 = 5.6 x 10–6; Ka3 = 3.32 x 10–10) with 0.10 M NaOH. Indicate
the volume needed to reach the first, second, and third equivalence
points and the pH at the half equivalence points for the three
titration regions.
3. Plot a schematic titration curve for acetic acid with NaOH.
Superimpose the titration curve of HCl on this graph. What are the
main differences? How can we determine the pKa of acetic acid from
its titration curve?
What is the pH of a buffer solution made by dissolving 10 g of
sodium acetate in 200 ml of 1M acetic acid? The Ka for acetic acid
id 1.7*10-5.
B. Calculate the pH of the solution if 10 ml of 0.100M HCl is
added to the solution.
C. What will the pH be if 5.00 ml of 0.150M NaOH was added to
solution in B?
D. Write the equation when an acid and a base are added to the...
Why
does the curve of titration of acetic acid begin at a higher pH
than the curve for HCl? Why does the pH at the center of the
rapidly rising region occur at a higher pH for the acetic acid
curve than for the HCl curve?
Consider a titration of 0.15M NaOH and 250 mL of 0.10M HBr.
What is the pH of the HBr solution before any base is
added?
What is the pH after 50 mL NaOH is added?
What is the pH after 125 mL NaOH is added?
What is the pH after 150 mL NaOH is added?