In: Chemistry
why is the lattice energy of potassium bromide more exothermic than the lattice energy of rubidium iodide in 510 words
You are comparing two chemicals (e.g. KBr and RbI) which are
known as IONIC COMPOUNDs, this means that THERE ARE IONs WHICH FORM
Polyatomic Cells of KBr and RbI.
Now, you get two clues treating about the BOND's ENERGY ABLE TO
CREATE DEBATED Polyatomic Cells STARTING FROM CONSTITUTING
UNITs.
Indeed, you may imagine that KBr AND/OR RbI STAY INSIDE A
CALORIMETER WHICH MEASURES THE HEAT SPENT BY A FLAME TO VOLATILIZE
IT AS FREE IONS
KBr(s) ---> K+(spread in flame) + Br-(spread in flame)
RbI(s) ---> Rb+(spread in flame) + I-(spread in flame)
the required energies result equal than Lattice energies
Why do different compounds exhibit different Lattice energies
ANSWER
The LATTICE ENERGY FOR an IONIC SOLID COMES FROM THE ELECTRICAL
ATTRACTIVE FORCE INTERACTING AMONG CONSTITUTING IONS. It is known
that those electrical forces depend on the basis of electrical
potential exerted by each ions, so THE SMALLER IONIC RADIUS THEN
THE STRONGER THE ACTING POTENTIAL.
IT IS EVIDENT THAT "KBr" INVOLVES IONS SMALLER THAN "RbI" DOES.