Question

In: Chemistry

Given the following unbalanced reaction and thermodynamics infromation, what is deltaGknot rxn at 85 degrees Celcius....

Given the following unbalanced reaction and thermodynamics infromation, what is deltaGknot rxn at 85 degrees Celcius. Please report your answer in kj/mol and to the correct number of significant figures.

C2H6 (g) + O2 (g) --> CO2 (g) + H2O (g)

deltaH values (kJ/mol): C2H6 (g) = -83.9; CO2 (g) = -394; H2O (g) = -242

deltaS values (J/mol): C2H6 (g) += 229; CO2 (g) = 214; H2O (g) = 189; O2 (g) =206

Side note: My answer was -2892.42, however it was wrong.

Solutions

Expert Solution

C2H6 (g) + O2 (g) CO2 (g) + H2O (g)

Balance the given reaction. On balancing we get:

C2H6 (g) + 7/2 O2 (g) 2 CO2 (g) + 3 H2O (g)

Go = Ho - TSo

Ho =Ho products - Ho reactants = [(-394 x 2) + (-242 x 3)] - [(-83.9)+0] = -1514 + 83.9 = -1430.1 Kj/mol

So =So products - So reactants = [(214x 2) + (3 x 189)] - [229+ (7/2 x 206)] = 428 + 567 - 950 = 45 KJ/mol

T = 85 + 273 = 358 K

Go = Ho - TSo = -1430.1 - (358 x 45) = - 17540.1 KJ/mol


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