Question

In: Chemistry

The ΔH°rxn for the following reaction is −114.2 kJ/mol. At what temperature (in °C) would the...

The ΔH°rxn for the following reaction is −114.2 kJ/mol. At what temperature (in °C) would the Kc for the reaction be 6.4 x 109? 2NO(g) + O2(g) ↔ 2NO2(g) Kc = 4.9 x 105 at 184°C

271°C
183°C
110°C
74°C

Solutions

Expert Solution

T1 = 1840C   = 184 + 273 = 457K

logK2/K1   = H/2.303R [1/T2 -1/T1]

log6.4*10^9/4.9*10^5   = -114200/2.303*8.314 [1/T2 -1/457]

log13061.22                 = -5964.34[1/T2-0.00218]

4.1159 /-5964.34    = [1/T2-0.00218]

-0.00069                = 1/T2-0.00218

-0.00069+0.00218   = 1/T2

1/T2                          = 0.00149

T2                              = 671K   = 671-273   = 3980C >>>>>answer


Related Solutions

A reaction has an activation energy of 12.2 kJ/mol at 25.0 °C. What temperature would you...
A reaction has an activation energy of 12.2 kJ/mol at 25.0 °C. What temperature would you need to run the reaction at for it to go 10 times faster?
Given the values of ΔH∘rxn, ΔS∘rxn, and Tbelow, determine ΔSuniv. A. ΔH∘rxn=− 118 kJ , ΔS∘rxn=...
Given the values of ΔH∘rxn, ΔS∘rxn, and Tbelow, determine ΔSuniv. A. ΔH∘rxn=− 118 kJ , ΔS∘rxn= 258 J/K , T= 294 K B. ΔH∘rxn= 118 kJ , ΔS∘rxn=− 258 J/K , T= 294 K C. ΔH∘rxn=− 118 kJ , ΔS∘rxn=− 258 J/K , T= 294 K . D. ΔH∘rxn=− 118 kJ , ΔS∘rxn=− 258 J/K , T= 545 K . Predict whether or not the reaction in part A will be spontaneous. Predict whether or not the reaction in part...
Consider the reaction N2(g) + 3H2(g) → 2NH3(g)ΔH o rxn = −92.6 kJ/mol If 2.0 moles...
Consider the reaction N2(g) + 3H2(g) → 2NH3(g)ΔH o rxn = −92.6 kJ/mol If 2.0 moles of N2 react with 6.0 moles of H2 to form NH3, calculate the work done (in joules) against a pressure of 1.0 atm at 25 degrees celsius. What is ΔU for this reaction? Assume the reaction goes to completion.
Consider the following set of reactions: N2 + 2O2→N2O4 ,ΔH=−8 kJ/mol N2 + O2→2NO ,ΔH=180 kJ/mol...
Consider the following set of reactions: N2 + 2O2→N2O4 ,ΔH=−8 kJ/mol N2 + O2→2NO ,ΔH=180 kJ/mol The equations given in the problem introduction can be added together to give the following reaction: overall: N2O4→2NO + O2 However, one of them must be reversed, reaction 1: N2 + 2O2→N2O4 What is the enthalpy for reaction 1 reversed? reaction 1 reversed: N2O4→N2 + 2O2 Express your answer numerically in kilojoules per mole. What is the enthalpy for reaction 2?
Use data in Appendix C in the textbook to calculate ΔH∘ in (kJ/mol) , ΔS∘ in...
Use data in Appendix C in the textbook to calculate ΔH∘ in (kJ/mol) , ΔS∘ in (j/mol-K) , and ΔG∘ in (kJ/mol) at 25 ∘C for each of the following reactions: 2P(g)+10HF(g)→2PF5(g)+5H2(g) Appendix C: P(g): dH:316.4; dG: 280.0; S:163.2 HF(g): dH: -268.61; dG: -270.70; S:173.51 PF5(g): dH:-1594.4; dG: -1520.7; S: 300.8 H2(g): dH:217.94; dG: 203.26; S: 114.60
c. For this reaction in heart muscle, ΔG°’ = +4.7 kJ/mol but ΔG = -0.6 kJ/mol....
c. For this reaction in heart muscle, ΔG°’ = +4.7 kJ/mol but ΔG = -0.6 kJ/mol. i. Explain, in words, how ΔG can be negative when ΔG°’ is positive. ii. What would be the ratio of 3PG to 2PG if the reaction were at equilibrium at 25°C? iii. What is the actual ratio of 3PG to 2PG in heart muscle (T = 37°C)?
For each of the following reactions, calculate ΔH∘rxn, ΔS∘rxn, and ΔG∘rxn at 25 ∘C. State whether...
For each of the following reactions, calculate ΔH∘rxn, ΔS∘rxn, and ΔG∘rxn at 25 ∘C. State whether or not the reaction is spontaneous. If the reaction is not spontaneous, would a change in temperature make it spontaneous? If so, should the temperature be raised or lowered from 25 ∘C?2CH4(g)→C2H6(g)+H2(g), Calculate ΔS∘rxn at 25 ∘C. 2NH3(g)→N2H4(g)+H2(g) Calculate ΔS∘rxn at 25 ∘C. N2(g)+O2(g)→2NO(g) Calculate ΔS∘rxn at 25 ∘C. 2KClO3(s)→2KCl(s)+3O2(g) Calculate ΔS∘rxn at 25 ∘C.
For each of the following reactions, calculate ΔH∘rxn, ΔS∘rxn, ΔG∘rxn at 25 ∘C. State whether or...
For each of the following reactions, calculate ΔH∘rxn, ΔS∘rxn, ΔG∘rxn at 25 ∘C. State whether or not the reaction is spontaneous. If the reaction is not spontaneous, would a change in temperature make it spontaneous? If so, should the temperature be raised or lowered from 25 ∘C? a) 2CH4(g)→C2H6(g)+H2(g) b) 2NH3(g)→N2H4(g)+H2(g) c) N2(g)+O2(g)→2NO(g) d) 2KClO3(s)→2KCl(s)+3O2(g) Can you please show equations. I am having so much trouble with these.
A certain reaction has an activation energy of 39.79 kJ/mol. At what Kelvin temperature will the...
A certain reaction has an activation energy of 39.79 kJ/mol. At what Kelvin temperature will the reaction proceed 6.50 times faster than it did at 339 K?
Determine ΔH°rxn at 25 °C for the reaction 2 HCN(g) → 2 C(graphite) + H2(g) +...
Determine ΔH°rxn at 25 °C for the reaction 2 HCN(g) → 2 C(graphite) + H2(g) + N2(g) given that the standard heat of formation (ΔH°f) of HCN(g) is 135.1 kJ/mol
ADVERTISEMENT
ADVERTISEMENT
ADVERTISEMENT