The reaction of methylacetate with water is shown below:
CH3CO2CH3 (aq) + H2O (l) ? CH3CO2H (aq) + CH3OH (aq)
The rate of the reaction is given by the following rate law: rate = k[H+][CH3CO2CH3] Consider one liter of solution that is 0.15 M CH3CO2CH3 (aq) and 0.015 M H+ (aq) at 25?C (a) For each change listed below state whether the rate of reaction increase, decreases or remains the same. Why?
(i) methylacetate (CH3CO2CH3) is added to the solution
2. The temperature is lowered
3 Water is added to the solution
For those 3 cases does the K increase or remain the same?
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Using the following precursors Li2CO3, ZrO2, Al2O3, La2O3, synthesize the following material Li6.25Al0.25La3Zr2O12.
(a.) How many grams off each precursor will be needed to make 3, 5 and 10 grams of Li6.4Al0.25La3Zr2O12?
(b.) What about 3 grams of Li6.4Al.20La3Zr1.4O12
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why did texans convene in 1875 to write yet another constitution?
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Materials Science and Engineering: How would you determine whether to use the ionic radius or the covalent/atomic radius to calculate the unit cell edge length and density for materials with the zincblende structure? Please explain your answer.
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1.
a) Calculate the moles of water produced when 0.1 mole of HCI reacts with 0.1 mole of NaOH. ( HCI + NaOH ---> H2O + NaCI )
b) If 0.5 moles of KOH are mixed with 1 mole of HNO3 how many moles of H2O are produced? ( KOH + HNO3 ---> KNO3 + H2O )
c) What would be the resulting temperature if 10 mL of water at 30 degrees Celsius is mixed with 100 mL of water at 90 degrees Celsius? Use the formula q=ms?t
d) One gallon of water at 0 degrees Celsius is mixed with 1 liter of water at 99.9 degrees Celsius. Using the formula q=ms?t calculate the resulting temperature in Fahrenheit and Kelvin.
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4000 m3/d of wastewater with a total suspended solids (TSS) concentration of 200 mg/L is subjected to treatment by coagulation and flocculation followed by sedimentation. The ferric chloride dose is 25 mg/L and the TSS removal is 90%. Estimate the daily volume of sludge produced if the sludge has a specific gravity of 1.05 and moisture content of 92.5%. The following reaction is applicable: 2FeCl3 + 3Ca(OH)2 ? 2Fe(OH)3 + 3CaCl2
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Provide comparison for liquid mixing expriments using different impellers and baffles and discuss how this affect the liquid and the power curves and power requirements.
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In a furnace, 76 lbs propane C3H8 are burned with 17.2% excess air for complete combustion. What is the percent CO2 in combustion products? Round your answer to the one decimal place.
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Cyclohexanol is a highly desired chemical precursor for the
production of nylon (billions of
kilograms of cyclohexanol are produced annually!). Industrially,
cyclohexanol can be formed by
the oxidation of cyclohexane over cobalt catalysts.
You have a vapor mixture of 50 mol.% cyclohexane and 50 mol.%
cyclohexanol. You want to
cool and condense your vapor mixture to form a vapor product and a
liquid product.
a. This problem contains a vapor-liquid system. Using the Gibbs
phase rule, determine the
number of degrees of freedom in a vapor-liquid equilibrium.
b. Your vapor mixture fills a drum that is 300 L in volume. At
atmospheric pressure and at
200°C, how many moles of vapor do you have?
c. You decide to feed your vapor mixture to the condenser at 5
mol/s. You measure your
vapor product and see that it comes out at 760 mmHg and 75 mol.%
cyclohexane. Using
Raoult’s law and Antoine’s Equation, determine your outlet
temperature.
d. Using the information given in the problem statement and Part C,
determine the
composition of your liquid phase and the molar flow rates of both
your liquid and vapor
products.
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In a closed system with a mobile border, a wet vapor with X = 1
is contained. The system undergoes heating keeping the plunger at
rest, however the pressure and temperature change to 2MPa and 800 °
c, respectively. Subsequently, the heating process continues at
constant pressure until the system reaches a temperature of 1300 °
c, generating an expansion process.
a) estimate the initial pressure of the system
b) calculate the work done by the steam
c) calculate the total heat transferred to the water vapor
d) represent the process on a T-v diagram
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Steam at 275ºC and 15.0 bar is contained in a rigid tank with the volume of 10.0 m3 . In a constantvolume cooling process, the pressure inside the tank drops to 1.8 bar and some of the steam condenses. Calculate 1) the temperature of the tank contents after the process, 2) the amount of steam condensed during the process (in kg), and 3) the amount of heat removed from the tank during the process.
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An electron microscope focuses electrons through magnetic lenses to observe objects at higher magnification than is possible with a light microscope. For any microscope, the smallest object that can be observed is one-half the wavelength of the radiation used. Thus, for example, the smallest object that can be observed with light of 400.0 nm is 2.00 ×10−7 m.
(a) What is the smallest object observable with an electron microscope using electrons moving at
8.70 ×104 m/s?
(b) At 1.40 × 107 m/s?
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discussion The difference baffles and no baffles in-tank mixer
Why not use baffles to have vortex?
Why use baffles not to have the vortex? And the size of baffles have What is the effect
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