Question

In: Chemistry

Using 2-bromobutane as your starting material, write a generic equation for each condition indicating the expected...

Using 2-bromobutane as your starting material, write a generic equation for each condition indicating the expected products and show the two possible mechanisms for nucleophilic substitutions.

1-bromobutane (n-butyl bromide)

1-chlorobutane

3-bromopropene (allyl bromide)

2-chlorobutane

2-bromobutane (sec-butyl bromide)

2-chloro-2-methylpropane

2-bromo-2-methylpropane (t-butyl-bromide)

chlorobenzene

Expert Solution

1-bromobutane(n-butyl bromide)=it will give SN2 mechanism beacause the degree of carbon is 1^o . SN2 requires less crowded substrate and Polar aprotic solvent for substitution.

1-chlorobutane : it will give SN2 mechanism beacause the degree of carbon is 1^o . SN2 requires less crowded substrate and Polar aprotic solvent for substitution.It will be slower than bromosubstitution because Br is better leavin group than Cl

3-bromopropene (allyl bromide) : It will give SN1and SN2 both , allylic substitution is favored

2-chlorobutane : it will give SN2 mechanism beacause the degree of carbon is 1^o . SN2 requires less crowded substrate and Polar aprotic solvent for substitution.It will be slower than bromosubstitution because Br is better leavin group than Cl

2-bromobutane (sec-butyl bromide) : it will give SN2 mechanism beacause the degree of carbon is 1^o . SN2 requires less crowded substrate and Polar aprotic solvent for substitution.It will be slower than bromosubstitution because Br is better leavin group than Cl

2-chloro-2-methylpropane : It will give SN1 best, beacause carbocation is the intermediate, so it will be more stable, greater is the stability greater is the rate of SN1

2-bromo-2-methylpropane (t-butyl-bromide): It will give SN1 best, beacause carbocation is the intermediate, so it will be more stable, greater is the stability greater is the rate of SN1

chlorobenzene : It will neither give SN1 nor SN2 , because of partial double bond character of halogen carbon bond in chlorobenzene

queen_honey_blossom answered 2 months ago

TRUE OR FALSE? Ordinarily,an event indicating a material condition arising after the reporting date requires inclusion...

TRUE OR FALSE? Ordinarily,an event indicating a material condition arising after the reporting date requires inclusion as an 'except for '?

Arrange the alkyl bromides in order of reactivity in each reaction: 1-bromobutane, 2-bromobutane, cyclohexabromide, t-butylbromide

Using benzene or toluene as the only aromatic organic starting material, devise a synthesis for each...

Using benzene or toluene as the only aromatic organic starting material, devise a synthesis for each of the following: a. o-chlorotoluene b. 3-bromonitrobenzene c. p-toluenesulfonic acid d. 2-chloronitrobenzene

Let's go through the right-hand rule. Starting with the generic vector cross-product equation point your forefinger...

Let's go through the right-hand rule. Starting with the generic vector cross-product equation point your forefinger of your right hand in the direction of , and point your middle finger in the direction of . Your thumb will then be pointing in the direction of . Part A Consider the specific example of a positive charge moving in the +x direction with the local magnetic field in the +y direction. In which direction is the magnetic force acting on the...

Complete each of the following as a net ionic equation, indicating whether a precipitate forms. If...

Complete each of the following as a net ionic equation, indicating whether a precipitate forms. If no reaction occurs, so state. Ca2++2Cl−+Pb2++2NO−3→ Al3++3NO−3+K++OH−→ Fe3++3NO−3+Na++OH−→

Please write the equation associated with (definition of) the Arrow- Pratt risk aversion coefficient, indicating the...

Please write the equation associated with (definition of) the Arrow- Pratt risk aversion coefficient, indicating the likely values (positive or negative) of the first and second derivatives of the utility function.

a) In your own words or using an example, describe each condition and its relevance for...

a) In your own words or using an example, describe each condition and its relevance for the three conditions for profitable price discrimination (1. have market power, 2. be able to identify submarkets, and 3. be able to separate submarkets). b) Suppose a perfectly price-discriminating firm faces demand function: ? = 22 − ? And has cost function: ? = 25 + 4? + (1 /2) ?^2 Identify the quantity he sells, the price(s) he charges, and the profits he...

Starting from the 2D time-independent Schr ̈odinger Equation, and using your knowledge of the 1D harmonic...

Starting from the 2D time-independent Schr ̈odinger Equation, and using your knowledge of the 1D harmonic oscillator, write down the normalized ground-state and the first excited state, with both position and time dependence included. Come up with a way of writing these states in shorthand using kets.

To write a Generic Collection class for Stack<E>, using the generic Node<E> from Lab 5, and...

To write a Generic Collection class for Stack<E>, using the generic Node<E> from Lab 5, and test it using a stack of Car, Integer, and String Stack<E> For Programming Lab 6, you are to write your own Generic Collection for a Stack that will use your Node<E> from Lab 5 UML for Stack<E> Stack<E> - top : Node<E> - numElements : int + Stack( ) + push( element : E ) : void + pop( ) : E + size(...

2. Write a balanced chemical equation for the reaction of one anion in each of the...

2. Write a balanced chemical equation for the reaction of one anion in each of the categories in question 1. A. a precipitation reaction B. a redox reaction C. an acid-base reaction D. a gas-forming reaction The Equations Given: Ca+2(aq) + SO4 -2(aq) ↔ CaSO4(s) Equation 1 Ca+2(aq) + CO3 -2(aq) ↔ CaCO3(s) Equation 2 CaCO3(s) + 2H+ (aq) → Ca+2(aq) + CO2(g) + H2O(l) Equation 3 CaSO4(s) + H+ (aq) → No Reaction (precipitate remains) Equation 4 2NO2 -...