Compute E0 for the process ZnY2- + 2e- = Zn(s) + Y4- where Y4-
is the...
Compute E0 for the process ZnY2- + 2e- = Zn(s) + Y4- where Y4-
is the completely deprotonated anion of EDTA. The formation
constant for ZnY2- is 3.2x1016.
Given the E0 values of the following two
half-reactions:
Zn à Zn2+ +
2e-
E0 = 0.763 volt
Fe à Fe2+ +
2e-
E0 = 0.441 volt
a)Write a balanced complete
oxidation-reduction reaction?
b)Explain whether the corrosion of
an iron pipe (i.e., Fe Fe2+) in the presence of
Zn/Zn2+ is possible or not (thermodynamically)?
c)Explain whether or not Zn will
protect the corrosion of iron pipe if metallic Zn is in contact
with the iron pipe?
13)) a) Consider the following half-reactions: Half-reaction E° (V) F2(g) + 2e- 2F-(aq) 2.870V 2H+(aq) + 2e- H2(g) 0.000V Zn2+(aq) + 2e- Zn(s) -0.763V
(1) The weakest oxidizing agent is: enter formula
(2) The strongest reducing agent is:
(3) The strongest oxidizing agent is:
(4) The weakest reducing agent is:
(5) Will F-(aq) reduce Zn2+(aq) to Zn(s)?
(6) Which species can be reduced by H2(g)? If none, leave box blank.
b))
Consider the following half-reactions: Half-reaction E° (V) Ag+(aq) +...
complete and balance the net ionic equations for reactions that
would occur:
Zn(s)+Mg2+(aq)--->
Zn(s)+Cu2+(aq)---->
Zn(s)+H+(aq)----->
Mg(s)+Zn2+(aq)----->
Mg(s)+Cu2+(aq)--->
Mg(s)+H+(aq)---->
Cu(s)+Zn2+(aq)---->
Cu(s)+Mg2+(aq)---->
Cu(s)+H+(aq)----->
The chemical reactions:
CuSO4(aq) + Zn(s) → ZnSO4(aq) + Cu(s) Zn(s) + H2SO4(aq) → ZnSO4(aq)
+ H2(g) The copper on the surface quickly reacts with oxygen
according to the following reaction: 2Cu(s) + O2(g) → 2CuO(s)
Experimental Procedure Dissolve
completely about 0.5 to 0.7 g of copper (II) sulphate pentahydrate
in about 10 to 20 mL of deionized water. Calculate the amount of
zinc powder that must be added to a copper sulfate solution so that
the sulfate completely reacts....
Co(s) → Co2+(aq) + 2e
Fe2+(aq) + 2e-→ Fe(s)
b) Calculate the standard cell potential for this voltaic cell.
c) Calculate the cell potential for this voltaic cell at 298 K if
it is constructed using solutions of 0.14 M Co(NO3)2 and 0.27 M
Fe(NO3)2. d) When looking at the magnitude of this potential, what
can be concluded about the electrochemical cell?
Reduction half-reaction
E∘ (V)
Ag+(aq)+e−→Ag(s)
0.80
Cu2+(aq)+2e−→Cu(s)
0.34
Sn4+(aq)+4e−→Sn(s)
0.15
2H+(aq)+2e−→H2(g)
0
Ni2+(aq)+2e−→Ni(s)
−0.26
Fe2+(aq)+2e−→Fe(s)
−0.45
Zn2+(aq)+2e−→Zn(s)
−0.76
Al3+(aq)+3e−→Al(s)
−1.66
Mg2+(aq)+2e−→Mg(s)
−2.37
1)
Use the table of standard reduction potentials given above to
calculate the equilibrium constant at standard temperature (25 ∘C)
for the following reaction: Fe(s)+Ni2+(aq)→Fe2+(aq)+Ni(s)
2)
Calculate the standard cell potential (E∘) for the
reaction
X(s)+Y+(aq)→X+(aq)+Y(s)
if K = 3.80×10−4.
Express your answer to three significant figures and include the
appropriate units.
A Zn-Cu battery is
constructed as follows at 25oC
Zn(s) |
Zn+2(aq) (0.20 M) ||
Cu+2(aq) (2.5 M) |
Cu(s)
The mass of each electrode is 200.0
gram and the volume of the electrolytes is 1.0 L
a) calculate the
cell potential of the cell
b) calculate the
mass of each electrode after 10.0 amp. of current has flowed for
10.0 hour Remember, the anode loses mass because of the oxidation
reaction while the cathode gains mass due to the...
Concerning the reaction: 2 HCl(aq) + Zn(s) H2(g) + ZnCl2(aq) A
piece of Zn with a mass of 3.2 g is placed in 233 mL of 0.19 M HCl
(aq). What mass in grams of H2(g) is produced in the cases of: a)
100. % yield b) 63.0 % yield
Zinc (Zn) metal reacts with hydrochloric acid (HCl) according to
the following reaction: Zn(s) + 2 HCl(aq) ZnCl2(aq) + H2(g)What
volume of H2 gas would be collected over water if 6.93 g Zn metal
were allowed to react with 25.0 mL of 1.0 M HCl at 25.0 oC? The
vapour pressure of water at 25.0 oC is 23.8 torr, and the pressure
of the laboratory is 1.00 atm