Question

In: Chemistry

a) Consider the following half-reactions: Half-reaction E° (V) F2(g) + 2e- 2F-(aq) 2.870V 2H+(aq) + 2e- H2(g) 0.000V Zn2+(aq) + 2e- Zn(s) -0.763V


13)) a) Consider the following half-reactions: Half-reaction E° (V) F2(g) + 2e- 2F-(aq) 2.870V 2H+(aq) + 2e- H2(g) 0.000V Zn2+(aq) + 2e- Zn(s) -0.763V

(1) The weakest oxidizing agent is: enter formula

(2) The strongest reducing agent is:

(3) The strongest oxidizing agent is:

(4) The weakest reducing agent is:

(5) Will F-(aq) reduce Zn2+(aq) to Zn(s)?

(6) Which species can be reduced by H2(g)? If none, leave box blank.

b))

Consider the following half-reactions: Half-reaction E° (V) Ag+(aq) + e- Ag(s) 0.799V Co2+(aq) + 2e- Co(s) -0.280V Fe2+(aq) + 2e- Fe(s) -0.440V

(1) The weakest oxidizing agent is: enter formula

(2) The strongest reducing agent is:

(3) The strongest oxidizing agent is:

(4) The weakest reducing agent is:

(5) Will Ag(s) reduce Fe2+(aq) to Fe(s)?

(6) Which species can be oxidized by Co2+(aq)? If none, leave box blank.

c))

Consider the following half-reactions: Half-reaction E° (V) I2(s) + 2e- 2I-(aq) 0.535V Co2+(aq) + 2e- Co(s) -0.280V Cr3+(aq) + 3e- Cr(s) -0.740V

(1) The strongest oxidizing agent is: enter formula

(2) The weakest oxidizing agent is:

(3) The weakest reducing agent is:

(4) The strongest reducing agent is:

(5) Will Cr3+(aq) oxidize I-(aq) to I2(s)?

(6) Which species can be oxidized by Co2+(aq)? If none, leave box blank.

Solutions

Expert Solution

13) a) E0 of F2/F- = 2.87V

            E0 of H+/H2 = 0.00V

             E0 of Zn+2/Zn = - 0.763V

The order is E0 of Zn+2/Zn = - 0.763V

                    E0 of H+/H2 = 0.00V

                    E0 of F2/F- = 2.87V

More SRP electrode acts as strongest oxidising agent and lease SrP electode acts as strongest reducing agent.

1) weakest oxidising agent = Zn

2) Strongest redcuing agent = Zn

3) strongest oxidising agent = F2

4) weakest reducing agent = F2

5) No, F- acts as strongest oxidising agent ;So it oxidises the other substances.[ it has more SRP than Zn]

6) F- ion reduced by H2

          H2 +2 F- ---------------- 2 H+ + F2

b)  E0 0f   Ag+/Ag = 0.799V

       E0 0f Co+2/Co = - 0.280V

       E0 of Fe+2/Fe = - 0.44V

The order is E0 of Fe+2/Fe = - 0.44V

                     E0 0f Co+2/Co = - 0.280V

                     E0 0f   Ag+/Ag = 0.799V

1) weakest oxidising agent = Fe

   2) strongest reducing agent = Fe

3) strongest oxidising agent = Ag

4) weakest reducing agent = Ag

5) N0

6) Fe is oxidised by CO+2

Fe + Co+2 --------------- Fe+2 + Co


Related Solutions

Consider the reaction: Zn(s) + 2 H+(aq) = Zn2+(aq) + H2(g) At 25C, calculate: a) ∆G˚...
Consider the reaction: Zn(s) + 2 H+(aq) = Zn2+(aq) + H2(g) At 25C, calculate: a) ∆G˚ for the reaction, given that: ∆Gf Zn(s) = 0, ∆Gf(H+) = 0, ∆Gf(H2) = 0, ∆Gf(Zn2+) = -147.1 kj/mol b) ∆G, when P(h2) = 750 mmHg, [Zn2+ aq] = 0.10 M, [H+] = 1.0 x 10^-4 M c) The pH when ∆G - -100 kJ, P(h2) = 0.922 atm, [Zn2+] = 0.200 M and the mass of Zn is 155 g.
Half-reaction E° (V) Hg2+(aq) + 2e- -----> Hg(l) 0.855V Ni2+(aq) + 2e- -----> Ni(s) -0.250V Zn2+(aq)...
Half-reaction E° (V) Hg2+(aq) + 2e- -----> Hg(l) 0.855V Ni2+(aq) + 2e- -----> Ni(s) -0.250V Zn2+(aq) + 2e- ----->  Zn(s) -0.763V (1) The weakest oxidizing agent is: ___   enter formula (2) The strongest reducing agent is: ___ (3) The strongest oxidizing agent is:___ (4) The weakest reducing agent is: ___ (5) Will Zn(s) reduce Hg2+(aq) to Hg(l)? _____(yes)(no) (6) Which species can be oxidized by Ni2+(aq)? ___ If none, leave box blank.
Reduction half-reaction E∘ (V) Ag+(aq)+e−→Ag(s) 0.80 Cu2+(aq)+2e−→Cu(s) 0.34 Sn4+(aq)+4e−→Sn(s) 0.15 2H+(aq)+2e−→H2(g) 0 Ni2+(aq)+2e−→Ni(s) −0.26 Fe2+(aq)+2e−→Fe(s) −0.45...
Reduction half-reaction E∘ (V) Ag+(aq)+e−→Ag(s) 0.80 Cu2+(aq)+2e−→Cu(s) 0.34 Sn4+(aq)+4e−→Sn(s) 0.15 2H+(aq)+2e−→H2(g) 0 Ni2+(aq)+2e−→Ni(s) −0.26 Fe2+(aq)+2e−→Fe(s) −0.45 Zn2+(aq)+2e−→Zn(s) −0.76 Al3+(aq)+3e−→Al(s) −1.66 Mg2+(aq)+2e−→Mg(s) −2.37 1) Use the table of standard reduction potentials given above to calculate the equilibrium constant at standard temperature (25 ∘C) for the following reaction: Fe(s)+Ni2+(aq)→Fe2+(aq)+Ni(s) 2) Calculate the standard cell potential (E∘) for the reaction X(s)+Y+(aq)→X+(aq)+Y(s) if K = 3.80×10−4. Express your answer to three significant figures and include the appropriate units.
Refer to this table of reduction potentials to answer the questions. Reduction half-reaction Potential (V) F2(g)+2e−→2F−(aq)...
Refer to this table of reduction potentials to answer the questions. Reduction half-reaction Potential (V) F2(g)+2e−→2F−(aq) +2.87 O2(g)+4H+(aq)+4e−→2H2O(l) +1.23 Br2(l)+2e−→2Br−(aq) +1.07 Ag++e−→Ag(s) +0.80 2H2O(l)+2e−→H2(g)+2OH−(aq) −0.83 Na+(aq)+e−→Na(s) −2.71 What is produced at each electrode in the electrolysis of an aqueous solution of both NaBr and AgF? H2(g), Ag(s), Na(s), O2(g), Br(l), F2(g) sort to respective designation below Anode, Cathode, Not produced
Given the following reaction, Cu2+(aq) + Zn(s) → Cu(s) + Zn2+(aq) E° = 1.10 V. Use...
Given the following reaction, Cu2+(aq) + Zn(s) → Cu(s) + Zn2+(aq) E° = 1.10 V. Use the Nernst equation to calculate the cell potential for the cell described with standard line notation below. Zn|Zn2+(0.5082 M)||Cu2+(0.2699 M)|Cu Units are not required. Report answer to three decimal places. Please explain all of your steps! Thanks!
Given: Pb2+(aq)+2e–⇌Pb(s);E°=–0.13 Mg2+(aq)+2e–⇌Mg(s);E°=–2.38V Ag+(aq)+e–⇌Ag(s);E°=0.80V 2H+(aq)+2e–⇌ H2(g);E°=0.00V Under standard-state conditions, which of the following species is the...
Given: Pb2+(aq)+2e–⇌Pb(s);E°=–0.13 Mg2+(aq)+2e–⇌Mg(s);E°=–2.38V Ag+(aq)+e–⇌Ag(s);E°=0.80V 2H+(aq)+2e–⇌ H2(g);E°=0.00V Under standard-state conditions, which of the following species is the best oxidizing agent? a. H b.Mg2+ c. Ag+ d. Pb e. Ag
NO3-(aq)+4H+(aq)+3e->NO(g)+2H2O(l) E=0.96V ClO2(g)+e->ClO2-(aq) E=0.95V Cu2+(aq)+2e->Cu(s) E=0.34V 2H+(aq)+2e->H2(g) E=0.00V Pb2+(aq)+2e->Pb(s) E=-0.13V Fe2+(aq)+2e->Fe(s) E=-0.45V Use appropriate data to...
NO3-(aq)+4H+(aq)+3e->NO(g)+2H2O(l) E=0.96V ClO2(g)+e->ClO2-(aq) E=0.95V Cu2+(aq)+2e->Cu(s) E=0.34V 2H+(aq)+2e->H2(g) E=0.00V Pb2+(aq)+2e->Pb(s) E=-0.13V Fe2+(aq)+2e->Fe(s) E=-0.45V Use appropriate data to calculate E?cell for the reaction. 3Cu(s)+2NO3-(aq)+8H+(aq)->3Cu2+(aq)+2NO(g)+4H2O(l) Express your answer using two decimal places.
Reduction Half Reaction E (V) Ag2MoO4(s) + 2e- ---> 2 Ag(s) + MoO42-(aq) 0.4573 V Ag+(aq)...
Reduction Half Reaction E (V) Ag2MoO4(s) + 2e- ---> 2 Ag(s) + MoO42-(aq) 0.4573 V Ag+(aq) + e- ---> Ag(s) 0.7996 V a.) Calculate the mass in grams of Ag2MoO4(s) that will dissolve in 2.0 L of water. b.) Calcilate the cell potential of: Ag(s) | Ag2MoO4(s) | MoO42-(aq) (0.010 M) || Ag+(aq) (0.010M) | Ag (s)
Given the E0 values of the following two half-reactions: Zn à Zn2+ + 2e-               E0 =...
Given the E0 values of the following two half-reactions: Zn à Zn2+ + 2e-               E0 = 0.763 volt Fe à Fe2+ + 2e-                E0 = 0.441 volt a)Write a balanced complete oxidation-reduction reaction? b)Explain whether the corrosion of an iron pipe (i.e., Fe Fe2+) in the presence of Zn/Zn2+ is possible or not (thermodynamically)? c)Explain whether or not Zn will protect the corrosion of iron pipe if metallic Zn is in contact with the iron pipe?
Half-reaction E° (V) Br2(l) + 2e- 2Br-(aq) 1.080V Sn2+(aq) + 2e- Sn(s) -0.140V Al3+(aq) + 3e-...
Half-reaction E° (V) Br2(l) + 2e- 2Br-(aq) 1.080V Sn2+(aq) + 2e- Sn(s) -0.140V Al3+(aq) + 3e- Al(s) -1.660V (1) The weakest oxidizing agent is: enter formula (2) The strongest reducing agent is: (3) The strongest oxidizing agent is: (4) The weakest reducing agent is: (5) Will Al(s) reduce Br2(l) to Br-(aq)? (6) Which species can be oxidized by Sn2+(aq)? If none, leave box blank.
ADVERTISEMENT
ADVERTISEMENT
ADVERTISEMENT