The water-gas shift reaction (CO + H2O à
CO2 + H2) occurs in a series of...
The water-gas shift reaction (CO + H2O à
CO2 + H2) occurs in a series of two
reactors. An equimolar mixture of steam and CO (stream 1) enters
the first reactor. The product stream from the first reactor
(stream 3) and an additional stream (stream 3) containing pure
steam enter the second reactor. The fractional conversion of CO in
the first reactor is 0.610, and the fractional conversion of CO in
the second reactor is 0.790. The product stream has a water (steam)
mole fraction of 0.210.
Draw and fully label a PFD for the process.
What is the fractional conversion of CO for the overall
process?
What is the ratio of the molar flow rate of stream 2 relative
to the molar flow rate of stream 1?
Put a box around the answers to the questions in b. and c. You
will receive 5 points for answering with the correct number of
significant digits.
Solutions
Expert Solution
I think you have mentioned both stream which are inputs to
reactor 2 as stream 2. I have taken pure steam stream as n2 and
stream leaving reactor 1 as n3
The water-gas shift reaction (CO + H2O à
CO2 + H2) occurs in a series of two
reactors. An equimolar mixture of steam and CO (stream 1) enters
the first reactor. The product stream from the first reactor
(stream 3) and an additional stream (stream 3) containing pure
steam enter the second reactor. The fractional conversion of CO in
the first reactor is 0.610, and the fractional conversion of CO in
the second reactor is 0.790. The product stream has...
Consider the water-shift gas reaction:
H2O + CO --> H2 + CO2
A closed reaction vessel maintained at 3000 degrees Celcius is
filled with 0.475 M H2 and 0.490 M CO2. At equilibrium, their
respective concentrations are 0.410 and 0.425 M.
PART A:
The following ratio represents
[H2][CO2] / [H2O][CO]
CHOOSE ONE OR MORE:
the law of mass action, the mass action expression, the
equilibrium constant expression, the equilibrium constant. none of
these
PART B:
which way must the system...
The water gas shift reaction involves the reaction of carbon
monoxide with water vapor to form carbon dioxide and hydrogen
gas:
CO(g) + H2O(g) → CO2(g) +
H2(g)
28.01 g CO and 9.01 g water vapor are combined in a reaction
vessel. At the end of the reaction, a total pressure of 945.3 torr
is found.
A.) Which gases are left at the end of the reaction?
B.) What are mole fractions of the gases left in the reaction
vessel...
The most important commercial process for generating hydrogen
gas is the water-gas shift reaction: CH4(g) + H2O(g) → CO(g) +
3H2(g)
a) Use tabulated thermodynamic data to find ΔG° for this
reaction at the standard temperature of 25°C.
b) Now calculate ΔG°1100 for this process when it
occurs at 1100 K.
The most important commercial process for generating hydrogen
gas is the water-gas shift reaction: CH4(g) + H2O(g) ? CO(g) +
3H2(g)
?G° for this reaction at the standard temperature of 25°C is
1.423×102 kJ. Now calculate ?G°1150 for this process when it occurs
at 1150 K.
Be sure to answer all parts. The water-gas shift reaction plays
a central role in the chemical methods for obtaining cleaner fuels
from coal: CO(g) + H2O(g) ⇌ CO2(g) + H2(g) A study was made in
which equilibrium was reached with [CO] = [H2O] = [H2] = 0.100 M
and [CO2] = 0.400 M. After 1.40 mol of H2 is added to the 2.00−L
container and equilibrium is reestablished, what are the new
concentrations of all the components?
Coke can be converted into CO�a fuel gas�in the reaction CO2 (g)
+ C (s) ? 2 CO (g) a coke that contains 84% carbon by mass and the
balance noncombustible ash is fed to a reactor with a
stoichiometric amount of CO2. The coke is fed at 77�F, and the CO2
enters at 400�F. Heat is transferred to the reactor in the amount
of 5859 Btu/lbm coke fed, the gaseous products and the solid
reactor effluent (the ash and...
The water-gas shift reaction plays a central role in the
chemical methods of obtaining clean fuels from coal.
CO (g) + H2O (g)= CO2 (g) + H2 (g)
A study was made in which equilibrium was reached with
[CO]=[H2O]=[H2]=0.100M and [CO2]=0.400M. After 0.800 mol of H2 is
added to the 2.00L container and equilibrium is reestablished, what
are the new concentrations of all the components?
CO2(g) + C(s) = 2 CO(g) a) Using the Bouduard reaction,
calculate gas composition in a furnace under 1 atm total pressure
and 1100 K. b) Under the same furnace conditions, is it possible to
reduce VO to V by CO? ( VO + CO = V + CO2 ) C(s) + O2(g) = CO2(g) o
GT = - 394100 – 0.84 T J/mol C(s) + ½ O2(g) = CO(g) o GT = -
111700 – 87.65 T J/mol V(s)...
Consider this reaction between solid carbon and carbon dioxide
gas. C(s) + CO2(g) ⇌ 2 CO(g); ΔH = +172.5 kJ/mol Please explain the
following: When chemical systems are subjected to stresses, the
equilibrium position may shift toward the reactants or products, or
it may be unaffected. How would each of the following changes
affect this equilibrium? 1. decreasing the temp 2. increasing the
CO2 3. increasing the volume of the container 4. adding C 5. adding
a catlyst Options: Would...