3. Estimate the values of Compressibility factor, enthalpy and
entropy for Benzene and cyclohexane if it...
3. Estimate the values of Compressibility factor, enthalpy and
entropy for Benzene and cyclohexane if it compressed from 650 K and
60 bar to 500 K and 110 bar.
Using the standard values of enthalpy changes (ΔH°) and entropy
change (ΔS°) to calculate the Gibbs free energy change for the
production of following metallic elements from their ore sources:
(a) 2ZnO(s) 2Zn(s) + O2(g) (b) 2CaO(s) 2Ca(s) + O2(g) (c) 2Al2O3(s)
4Al(s) + 3O2(g) (d) 2MgO(s) 2Mg(s) + O2(g)
The azeotrope of the benzene-cyclohexane system has a
composition of 53.2 mol% benzene with a boiling point of 350.6 K at
101.3 kPa. At this temperature the vapour pressure of benzene (1)
is 100.59 kPa and the vapour pressure of cyclohexane (2) is 99.27
kPa. Determine the activity coefficient for the solution containing
10 mol% benzene
3.- ENTROPY EXERCISES.
From the absolute entropy values calculate the standard entropy
changes (ΔS °) of the following reactions at 25 C
a.-
CaCO3(s) →→→ CaO
(s) +
CO2(g)
b.-
N2(g)
+
3H2(g)
→→→ 2NH3(g)
c.-
H2(g)
+ Cl2(g)
→→→ 2HCl (g)
TABLE OF VALUES OF STANDARD ENTROPY (S °):
COMPOUND
Standard Entropy (S°): J/ K-mol
CaCO3(s)
92.9
CaO (s)
39.8
CO2(g)
213.6
N2(g)
192
H2(g)
131
NH3(g)
193
Cl2(g)
223
HCl (g)
187
Cyclohexane can be produced by reacting benzene with hydrogen:
??6??6 + 3 ??2 ? ??6??12 A fresh feed of benzene combined with 20%
excess hydrogen is blended with a recycle stream and fed to a
reactor. The recycle stream is 22.74% benzene and the rest
hydrogen, on a molar basis. The reactor achieves a single-pass
conversion of benzene of 20%. The reactor effluent is sent to a
separator, where one stream is the recycle and the other is the
product....
A. There is a beaker of benzene and one of toluene. Is the
entropy higher for two individual beakers or higher if they are
mixed together and why?
B. If the mixing the two substances together, what mole fraction
of each maximizes the entropy? Explain reason and then show
mathematically.
Calculate the standard heat of reaction for the dehydrogenation
of cyclohexane to benzene in the vapor phase.
C6H12 = C6H6 + 3
H2
The reactor for this system operates at 70% conversion of
cyclohexane. If the feed rate is 4000 kg of pure
C6H12 per hour at 100oC, determine the rate
of heat addition to or removal from the reactor that is required if
the product gases leave the reactor at 300oC.
1.a.) The heat of hydrogenation of cyclohexane is -120kJ/mol.
The heat of hydrogenation benzene is -208kJ/mol. Is the heat of
hydrogenation of benzene more or less than you would expect
1.b.) This is the value different from the expected?