Question

In: Chemistry

Determine the calorimeter heat capacity using the known enthalpy of combustion of benzoic acid. Sample Tablet...

Determine the calorimeter heat capacity using the known enthalpy of combustion of benzoic acid.

Sample

Tablet Weight(g)

Initial Temp(K)

Final Temp(K)

Wirelength(cm)

Wire left length(cm)

Benzoic Acid

0.99

294.35

296.75

9.3

0

Benzoic Acid(2)

1.01

295.25

297.85

9.3

0.8

Naphthalene

.98

294.95

298.75

9.3

1.0

Naphthalene(2)

1.07

295.05

301.95

9.3

0.5

Solutions

Expert Solution

Determination of calorimeter heat capacity

moles of benzoic acid = 0.99 g/122 g/mol

                                    = 0.008 mols

Enthalpy of combustion of benzoic acid = 3226 kJ/mol

So,

Heat released to calorimeter = 3226 kJ/mol x 0.008 mol

                                               = 25.808 kJ

Heat capacity of calorimeter = 25.808/(296.75 - 294.35)

                                              = 10.753 kJ/K


Related Solutions

The enthalpy of combustion, ΔH, for benzoic acid, C6H5COOH, is -3226 kJ/mol. When a sample of...
The enthalpy of combustion, ΔH, for benzoic acid, C6H5COOH, is -3226 kJ/mol. When a sample of benzoic acid was burned in a calorimeter (at constant pressure), the temperature of the calorimeter and contents rose from 23.20°C to 28.40°C. The heat capacity of the calorimeter and contents was 12.41 kJ/ °C. What mass of benzoic acid was burned?
Q) The combustion of 3.07 g of hydrogen in a bomb calorimeter with a heat capacity...
Q) The combustion of 3.07 g of hydrogen in a bomb calorimeter with a heat capacity of 26.24 kJ/K results in a rise in temperature from 18.43 °C to 35.02 °C. Calculate the heat of combustion (in kJ/g) of the hydrogen. Report your answer to three significant figures. Please show your work and equations. Thank you!
Physical Chemistry Thermodynamics: The enthalpy of combustion of benzoic acid (C6H5COOH) is commonly used as the...
Physical Chemistry Thermodynamics: The enthalpy of combustion of benzoic acid (C6H5COOH) is commonly used as the standard for calibrating constant-volume bomb calorimeters; its value has been accurately determined to be —3226.7 kJ mol-1, (a) When 0.9862 g of benzoic acid was oxidized, the temperature rose from 21.84°C to 25.67°C. What is the heat capacity of the calorimeter? (b) In a separate experiment, 0.4654 g of glucose (C6H1206) was oxidized in the same calorimeter, and the temperature rose from 21.22°C to...
The heat of combustion of benzoic acid (C6H5COOH) is -3226 kJ/mol. When 0.919 g of benzoic...
The heat of combustion of benzoic acid (C6H5COOH) is -3226 kJ/mol. When 0.919 g of benzoic acid was burned in a bomb calorimeter, the temperature of the calorimeter (including its contents) rose from 22.25 °C to 26.27 °C. What is the heat capacity (calorimeter constant) of the calorimeter?
Heat of Combustion and Enthalpy The heat of combustion of hexane is 45.6 kj/g. If you...
Heat of Combustion and Enthalpy The heat of combustion of hexane is 45.6 kj/g. If you burn all of a 1.20 g sample of hexane, and all of the heat is transferred to a pot of water determine the following: (a)The amount of heat in J, and the sign of the energy change (b)The amount of heat absorbed in water: (c) The final temperature of water if there are 250 g of water in the pot, and the intial water...
An ice “calorimeter” can be used to determine the specific heat capacity of a metal. A...
An ice “calorimeter” can be used to determine the specific heat capacity of a metal. A piece of hot metal is        dropped onto a weighed quantity of ice. The energy transferred from the metal to the ice can be determined        from the amount of ice melted. Suppose you heat a 9.36-g piece of platinum to 98.6 °C in a boiling water bath        and then drop it onto ice at 0.0 °C. When the temperature of the metal...
A. When a 0.235-g sample of benzoic acid is combusted in a bomb calorimeter, the temperature...
A. When a 0.235-g sample of benzoic acid is combusted in a bomb calorimeter, the temperature rises 1.644 ∘C . When a 0.275-g sample of caffeine, C8H10O2N4, is burned, the temperature rises 1.585 ∘C . Using the value 26.38 kJ/g for the heat of combustion of benzoic acid, calculate the heat of combustion per mole of caffeine at constant volume. B. Assuming that there is an uncertainty of 0.002 ∘C in each temperature reading and that the masses of samples...
A calorimeter has negligible heat capacity. When 50 ml 0.5 of a strong a strong acid...
A calorimeter has negligible heat capacity. When 50 ml 0.5 of a strong a strong acid HCl (at 19.6° c) is mixed with 50 ml 0.5 of a strong base KOH (at 19.6°C), the final temperature of the solution is 23.1 °C. Assume the density of solution is 1.o g/ml and its specific heat is 4.18 j/g-°C. The heat of the reaction is; a) -2.591 kj b) -2.701 kj C) 2.591 kj d) 2.701 kj e) -1.463 kj
Write the balanced equation for the combustion of aqueous citric acid. Determine the standard molar enthalpy...
Write the balanced equation for the combustion of aqueous citric acid. Determine the standard molar enthalpy of aqueous citric acid. citric acid can constitute 8% of the dry weight of limes if a typical lime contains 30 ml of juice how much energy is released when one lime is combusted?
In the specific heat experiment, critical factors are the heat capacity of the calorimeter, the temperature...
In the specific heat experiment, critical factors are the heat capacity of the calorimeter, the temperature of the holt sample, and the final temperature of the calorimeter. What effect could influence the temperature of the hot sample at the instant it is inserted into the calorimeter? What issues surround the measurement of the final calorimeter temperature?
ADVERTISEMENT
ADVERTISEMENT
ADVERTISEMENT