In: Chemistry
a. Calculate the energy transferred when the temperature of 75 cm3 of water rises from 23 °C to 54 °C.
b. When 8 g of sodium chloride is dissolved in 40 cm3 of water the temperature falls from 22 °C to 20.5 °C. Calculate the energy absorbed by the solution when sodium chloride dissolves.
c. A student added 50 cm3 of sodium hydroxide to 50 cm3 of hydrochloric acid. Both solutions were at 18 °C to start with. When the solutions were mixed a reaction occurred. The temperature rose to 33 °C. Calculate the energy released in this reaction.
Ans A)
Given,
( Temperature ) T1 = 23°C
T2 = 54° C
75g of water= 75cm^3 of water
q =?
We know that
q = mc∆T
Here = ∆T = T2-T1
q = 75 x 4.186 x (54- 23)
q= 9732.45J
Hence , energy transferred = 9.7324 KJ
Ans B) Given ,
Mass ( m) = 8g
T1 = 22° C
T2 = 20.5 °C
mass of 40cm3 = 40g
According to the formula
q = mc∆T
q = 40 x 4.186 x (20.5- 22)
q = -251.16J
Hence , energy absorbed = 251.16J for 8g of NaOH
And for 1mole NaOH, heat absorbed = 1255.8J/mol
Ans C) Given ,
T1 = 18 ° C
T2 = 33° C
V1 { V Of NaOH} = 50cm^ 3
V2 { V of HCl} = 50cm^3
Total Volume = 50cm^3 + 50cm^ 3 = 100cm^3
V = 100cm^3
Here , we assume the density = 1g/cm^3
mass = 100g
Let the specific heat be equal to the water
So, q = mc∆T
q = 100 x 4.186 x (33- 18)
q = 6279J
Hence , energy released = 6.279KJ.
So, q = mc∆T
q = 100 x 4.186 x (33- 18)
q = 6279J
Hence , energy released = 6.279KJ.