- the chemistry of boran more closely resembles the chemistry of
silicon than that of the other elements in Group 13 of the periodic
table.
- the chemical reactivity of boron depends on its form, generally
the crystalline form is far less reactive than the amorphous
form.
for example, the amorphous powder is oxidized slowly in air at
room temperatures and ignites spontaneously at high temperatures to
form an oxide.B2O3
4B+3O2 (g) --> 2B2O3 (s)
- Boron does not reacts with water under normal conditions
- Boron reacts vigorously with halogens fluorine F2, chlorine
Cl2,bromine Br2 to form the trihalide boron(III)
2B(s) + F2 (g) ---> 2BF3(g)
2B(s)
+ Cl2 (g) ---> 2BCl3(g)
2B(s) + I2 (g) ---> 2BI3(g)
- crystaline born does not reacts with conc.HCl or HF, powdered
boron oxidises slowly when treated with concentrated H2SO4
- Boron used as Deoxidizer or Degasifier in metallurgy.
- Because it absorbs neutrons, it is used in the shielding
material and in some control rods of nuclear reactors.
- Boron does not occur free in nature. Large deposits of borax,
kermite, colemanite and occurs in the mineral tourmaline.