Question

In: Chemistry

For each system listed in the first column of the table below, decide whether the change...

For each system listed in the first column of the table below, decide whether the change described in the second column will increase the entropy S of the system, decrease, or leave S unchanged. If you don’t have enough information to deiced, check the “not enough information” button in the last column

System

Change

ϫS

A few moles of carbon CO2 gas

The carbon dioxide is cooled from -2 C to -9 Cwhile the volume is held constant at 10 L

ϫS < 0

ϫS = 0

ϫS > 0

not enough information

A few grams of liquid NH

The ammonia evaporates at a constant temperature of -3.0 C

ϫS < 0

ϫS = 0

ϫS > 0

not enough information

A few moles of CO2 gas

The carbon dioxide is heated from -1.0 C to 69 C and is also compressed from a volume of 9 L to a volume of 4 L

ϫS < 0

ϫS = 0

ϫS > 0

not enough information

Solutions

Expert Solution

Entropy is the measure of disorderness of system.

Entropy os gas > liquid > solid

Increase in temperature increases the entropy

Increase in volume increases the entropy

increase in pressure decreases the entropy

Now,

1. Since temperature of CO2 is decreased rom - 2 to - 9, the randomness of the system decreases and hence the entropy. So, delta S < 0

2. Since ammonia is geeting evaporates, its randomness will increase and hence the entropy. SO, deltaS > 0

3. Increase in temperature increases the entropy but decrease in volume decreases the entropy. Hence change in entropy depends on the net effect of temperature and volume.

SO, deltaS > 0


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