Question

In: Chemistry

Calculate the concentration of Ca2+ in a saturated solution of CaSO4 that contains 0.1 M CaCl2....

Calculate the concentration of Ca2+ in a saturated solution of CaSO4 that contains 0.1 M CaCl2. Ksp= 2.5*10-5 for CaSO4.

Solutions

Expert Solution

CaCl2(aq) ----------------> Ca^2+ (aq) + 2Cl^- (aq)

0.1M ------------------------ 0.1M

   CaSO4(s) ---------------> Ca^2+ (aq) + SO4^2- (aq)

-------------------------------   x +0.1------------ x

Ksp   = [Ca^2+][SO4^2-]

2.5*10^-5 = (x+0.1)(x)

2.5*10^-5 = (0.1)(x)                       [ x + 0.1 = 0.1, x<<<<<0.1]

x   = 2.5*10^-4

The concentration of Ca^2+ = x + 0.1

                                           = 2.5*10^-4 + 0.1

                                            = 0.10025M >>>>answer


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