In: Chemistry
What volume of air will be expelled from a vessel containing 400 cm3 at 7°C when it is heated to 27° C at the same pressure ?
Given: The volume and temperature
To find: The amount of volume expelled
Solution: As the pressure is constant, we can apply Charle's law.
\(\frac{V_{1}}{T_{1}}=\frac{V_{2}}{T_{2}} \ldots \ldots \ldots \ldots \ldots \ldots \ldots \ldots \ldots . .\) (i)
Now,
\(\mathrm{V}_{1}\) =initial volume \(=400 \mathrm{~cm}^{3}\)
\(\mathrm{T}_{1}\) =initial temperature \(=(273+7) \mathrm{K}=280 \mathrm{~K}\)
\(\mathrm{V}_{2}=\) final volume =unknown
\(\mathrm{T}_{2}=\) final temperature \(=(273+27)=300 \mathrm{~K}\)
Now from equation-(i)
\(\frac{400}{280}=\frac{V_{2}}{300}\)
\(V_{2}=428.6 \mathrm{~cm}^{3}\)
Hence, the volume expelled out \(=(428.6-400) \mathrm{cm}^{3}=28.6 \mathrm{~cm}^{3}\)
The volume of the air will be 28.6cm3