In: Chemistry
Calculate the binding energy per nucleon (in J) for 2H and 3H. The atomic masses are 2.014102 u for 2H, and 3.016049 u for 3H. (Enter unrounded values. Assume that the mass of 11H = 1.007825 u,mp = 1.007275 u, mn = 1.008666 u, and me = 0.000549 u, respectively.)
Atomic mass of 2H = 2.017102 u
Atomic mass of 3H = 3.016049u
Mass of proton (mp) =1.007275 u
Mass of neutron (mn) =1.008666u
Mass of electron (me) =0.000549u
Binding energy per nucleon =?
Calculated mass of 2H = mass of 1proton +mass of 1 electron +mass of 1 neutron
=1.007275 u +0.000549u +1.008666u = 2.01649u
Actual mass of 2H =2.014102 u
Mass defect (delta M) = calculated mass - actual mass
=2.01649u - 2.014102u =0.002388u
For a mass defect of 1amu energy released =931.5Mev
For a mass defect of 0.002388u, energy released =931.5MeV× 0.002388=2.224422 MeV
Thus binding of the nuclide =2.224422MeV
Binding energy per nucleon = 2.224422MeV /2=1.112211MeV
1Mev = 1.602×10-13joules
1.112211MeV =1.112211×1.602×10-13= 1.7816×10-13 Joule
Binding energy of 2H =1.7816×10-13joule
For 3H calculations are as follow:
Calculated mass of 3H = mass of 1proton +mass of 1electron +mass of 2neutrons
=1.007275 u+0.000549u +2×1.008666= 3.025156
Actual mass of 3H = 3.016049u
Mass defect = calculated mass - Actual mass
= 3.025156 u- 3.016049u = 0.009107u
For a mass defect of 1u energy released =931.5MeV
For a mass defect of 0.009107u, energy released =0.009107×931.5MeV =8.4831705MeV
Binding energy of nuclide = 8.4831705 MeV
Binding energy per nucleon = 8.4831705MeV/3 =2.8277235MeV
1MeV = 1.602×10-13 joule
2.8277235MeV = 2.8277235×1.602×10-13 = =4.53×10-13joule
Thus binding energy of 3H =4.53×10-13 joule
For calculating binding energy per nucleon , divide the binding energy with number of nucleon (sum of neutron and proton which is equal to mass number) for 2H nucleon =2and for 3H nucleon =3