Question

In: Chemistry

Calculate the binding energy per nucleon (in J) for 2H and 3H. The atomic masses are...

Calculate the binding energy per nucleon (in J) for 2H and 3H. The atomic masses are 2.014102 u for 2H, and 3.016049 u for 3H. (Enter unrounded values. Assume that the mass of 11H = 1.007825 u,mp = 1.007275 u, mn = 1.008666 u, and me = 0.000549 u, respectively.)

Solutions

Expert Solution

Atomic mass of 2H = 2.017102 u

Atomic mass of 3H = 3.016049u

Mass of proton (mp) =1.007275 u

Mass of neutron (mn) =1.008666u

Mass of electron (me) =0.000549u

Binding energy per nucleon =?

Calculated mass of 2H = mass of 1proton +mass of 1 electron +mass of 1 neutron

=1.007275 u +0.000549u +1.008666u = 2.01649u

Actual mass of 2H =2.014102 u

Mass defect (delta M) = calculated mass - actual mass

=2.01649u - 2.014102u =0.002388u

For a mass defect of 1amu energy released =931.5Mev

For a mass defect of 0.002388u, energy released =931.5MeV× 0.002388=2.224422 MeV

Thus binding of the nuclide =2.224422MeV

Binding energy per nucleon = 2.224422MeV /2=1.112211MeV

1Mev = 1.602×10-13joules

1.112211MeV =1.112211×1.602×10-13= 1.7816×10-13 Joule

Binding energy of 2H =1.7816×10-13joule

For 3H calculations are as follow:

Calculated mass of 3H = mass of 1proton +mass of 1electron +mass of 2neutrons

=1.007275 u+0.000549u +2×1.008666= 3.025156

Actual mass of 3H = 3.016049u

Mass defect = calculated mass - Actual mass

= 3.025156 u- 3.016049u = 0.009107u

For a mass defect of 1u energy released =931.5MeV

For a mass defect of 0.009107u, energy released =0.009107×931.5MeV =8.4831705MeV

Binding energy of nuclide = 8.4831705 MeV

Binding energy per nucleon = 8.4831705MeV/3 =2.8277235MeV

1MeV = 1.602×10-13 joule

​​​​​​2.8277235MeV = 2.8277235×1.602×10-13 = =4.53×10-13joule

Thus binding energy of 3H =4.53×10-13 joule

For calculating binding energy per nucleon , divide the binding energy with number of nucleon (sum of neutron and proton which is equal to mass number) for 2H nucleon =2and for 3H nucleon =3


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