Question

In: Chemistry

Part1. Calculate the nuclear binding energy (in J) and the nuclear binding energy per nucleon of...

Part1. Calculate the nuclear binding energy (in J) and the nuclear binding energy per nucleon of

241 Pu
94

(241.0568453 amu).

Part 2.

A freshly isolated sample of 90Y was found to have an activity of 8.2 × 105 disintegrations per minute at 1:00 p.m. on December 3, 2006. At 2:15 p.m. on December 17, 2006, its activity was measured again and found to be 2.2 × 104 disintegrations per minute. Calculate the half-life of 90Y.



Solutions

Expert Solution

1) First we find mass defect = ( theoretically calculated mass) - experimentally observed mass

241 Pu has 94 p ( protons) and 241-94 = 147 n ( neutrons)

theoretical mass = numper of p x mass of p + number of n x mass of n

                  = 94 x ( 1.0072766) + ( 147 x 1.0086654)

                  = 242.957814 amu

mass defect = 242.957814 - 241.0568453 = 1.909689 amu = 1.909689 x 1.6605388 x 10^ -27 kg

             = 3.15663 x 10^ -27 kg

Binding enegy = mass defect x speed of light ^2 /

                                 = ( 3.1566x10^ -27 x (3x10^8)^2

                             = 2.84 x 10^ -10 J

Binding energy per nucloen = ( 2.84x10^ -10 ) /241 = 1.179 x 10^ -11 J/nucleon

2) radio active deca followst 1st order kinetcis

k = ( 1/t) ln ( a/a-x) where a = 8.2x10^5 , a-x = 2.2x10^4 ,

t = time = dec 17 2.15 pm - dec 3 1pm = 14 days + 1hr + 15 min = ( 14 x 24x60) min + 60 min + 15 min

      = 20235 min

now k = ( 1/20235) ln ( 8.2x10^5) / ( 2.2x10^4)

   = 0.000178812

half life = ln 2/ k = ln 2 / ( 0.000178812) = 3876.4 min


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