Question

In: Chemistry

Given the following information Ag+(aq) + e- ↔ Ag(s)   Eºred = 0.799 V Ag2CrO4(s) + 2e-...

  1. Given the following information

    Ag+(aq) + e- ↔ Ag(s)   red = 0.799 V

    Ag2CrO4(s) + 2e- ↔ 2Ag(s) + CrO42-(aq) red = 0.450 V

    Determine the equilibrium constant at 25 °C for the reaction below:

    Ag2CrO4(s) ↔ 2Ag+(aq) + CrO42-(aq)

    1.

    9 × 10-18

    2.

    1.6 × 10-12

    3.

    1.2 × 10-6

    4.

    1.6 × 1015

    5.

    1.7 × 1039

  1. Examine the following half reactions and select the strongest oxidizing agent among the species listed.

    Cr2+(aq) + 2e- ↔ Cr(s) Eºred = -0.913 V

    Sr2+(aq) + 2e- ↔ Sr(s) Eºred = -2.89 V

    Fe2+(aq) + 2e- ↔ Fe(s) Eºred = -0.447 V

    Co2+(aq) + 2e- ↔ Co(s) Eºred = -0.28 V

    1.

    Cr2+(aq)

    2.

    Fe(s)

    3.

    Fe2+(aq)

    4.

    Sr2+(aq)

    5.

    Co2+(aq)

2 points   

QUESTION 5

  1. Which of the changes below will increase the voltage of the following cell?

    Co | Co2+ (0.010M) || H+ (0.010 M) | H2(0.50 atm) | Pt

    1.

    Increase the pressure of H2 from 0.50 atm to 1.0 atm

    2.

    Increase the concentration of H+ from 0.010 to 0.050 M.

    3.

    Increase the mass of Co electrode from 12 grams to 15 g.

    4.

    Increase the concentration of Co2+ from 0.010 M to 0.40 M.

Solutions

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