Which spectroscopy is more sensitive: fluorescence or
absorption? Why? (2) Between fluorescence and phosphorescence:
which one has a higher intensity? Which one lasts longer?
a. what is the difference between a flourescence
excitation spectrum and a fluorescence emission spectrum?. which
resembles an absorption spectrum.
b. consider a molecule that can fluoresce from the s1
state and phosphoresce from the t1state. which is emitted at longer
wavelength?make a sketch showing absorption fluorescence and
phosphorescence on a single spectrum.
Describe at least one analytical technique that you could use
that is more sensitive than Raman spectroscopy, FTIR spectroscopy,
and energy-dispersive X-ray spectroscopy (EDS) analyses, but that
might be destructive in its analysis of the material. Describe the
benefits and other limitations of this technique.
Describe two major reasons why fluorescence spectrophotometry is
a very sensitive analytical technique? (hint, one of the reasons
involves the equation I = KP0C)
If you wish to analyze a molecule using fluorescence
spectrophotometry but that molecule does not fluoresce, what can
you do?
What characteristics of a molecule make it likely to
fluoresce?
1. Describe four ways to shift the position of the equilibrium
system. Which of the ways affect the value of the equilibrium
constant?
2. A solution is prepared by mixing 35.0 mL of .00120M Fe(NO3)3
and 15.0mL of .00180M KSCN.
a.Use your average value of Kc (1.68x10^2) to predict the
equilibrium concentration of FeSCN^2+. Show all work with an I
Delta E table and the set-up and solution of the reuired quadratic
equation.
b. Calculate the absorbance expected for this...
A) The price of which of the following will be more sensitive to
changes in interest rates. Explain your answer. Proper explanation
/ calculations required
Bond X. 2-year 15% coupon bond with a face value of
$1000 that pays semi-annual coupons and is trading at a yield of
26%
Or
Bond Y. A Zero-Coupon Bond that has a maturity of 18 months
B) What is the price of the Bond X . above ?
C) Would your answer to part A change...
In what ways is IRR more useful than NPV? In what ways is NPV
more useful than IRR? Or you could view this question as asking for
the pros and cons of each calculation.
Which optical interferometer do you like most. Describe the
optical layout and the working of this interferometer including one
application where it is used. Draw diagrams as needed