For each of the following categories of compounds, indicate the type of liquid chromatography that could be used to separate analytes in that category. (Drag the appropriate chromatography label to the blank next to the category. Only one label applies to each category, but a label may be used more than once).
Seperation Mode Analyte Category
Fm>2000,soluble in octane,size10 nm
Fm>2000, soluble in butanol, size 100 nm
Fm>2000, soluble in water,nonionic,size 10 nm
Fm<2000, soluble in in ethanol
Fm<2000 , soluble in water, ion-paired
Fm<2000, soluble in water, ionic
Choices:
ion -exchange
Bonded-reverse phase
Adsorption
Bonded normal phase
Molecular exculsion
In: Chemistry
Give the net ionic equations for the following:
a. AgCl + ZnCl2
b. PbCl2 + Hg2Cl2
c. Cd(NO3)2 + AgNO3
d. HCl + HNO3
e. Hg2(NO3)2 + Hg(NO3)2
In: Chemistry
A voltaic cell consists of an Al/Al3+ half-cell and a Cd/Cd2+ half-cell. Calculate Ecell when [Cd2+] = 0.00303 M and [Al3+] = 0.47 M. You should use the reduction potentials for Al3+ is -1.66 V and for Cd2+ is -0.40 V.
In: Chemistry
Consider the reaction A -> products at 312 K.
For this reaction it was observed that the first three half lives were 10.7 h, 5.35 h, and 2.675 h when [A] 2.873M. How long will it take for [A] to decrease by 47%?
Time for [A] to decrease by 47% (in hours) = Anwser is 10.1h need help on how to get this anwser.
In: Chemistry
15) Name two materials that are theoretically strong enough to build a space elevator.?
Please explain in clear words. Thanks
In: Chemistry
Starting from the first and second law of thermodynamics, derive the fundamental equation for A in its natural variables. a) Derive the Maxwell relation that s related to this equation. b) Show that for df= gdx + hdy we have an exact equation if:
In: Chemistry
Without doing detailed calculations, indicate which of the following electron transitions in the hydrogen atom results in the emission of light of the longest wavelength. Explain why.
a. from n = 1 to n = 2
b. from n = 4 to n = 3
c. from n = 1 to n = 6
d. from n = 3 to n = 2
In: Chemistry
Consider the titration of 100.0 mL of 0.016 M HOCl (Ka=3.5×10?8) with 0.0400 M NaOH.
1) How many milliliters of 0.0400 M NaOH are required to reach the equivalence point?
2) Calculate the pH after the addition of 10.0 mL of 0.0400 M NaOH.
3) Calculate the pH halfway to the equivalence point .
4) Calculate the pH at the equivalence point.
thank you!
In: Chemistry
The law of mass conservation is another fundamental law in chemistry. this law states that matter can neither be created or destroyed, which means that in a chemical reactions where all the reactant is converted into product, the mass of reactant must be equaly equal to mass of product produced. A) consider 2 precipitation reactions B) experimental procedure that you can use in lab C) contemplate how you might visually represent this data (I) what variables might you need to plot (ii) how would your choice of graph illistrate the law of mass conservation
In: Chemistry
How many grams of dipotassium succinate trihydrate (K2C4H4O4·3H2O, MW = 248.32 g/mol) must be added to 800.0 mL of a 0.0417 M succinic acid solution to produce a pH of 5.974? Succinic acid has pKa values of 4.207 (pKa1) and 5.636 (pKa2).
In: Chemistry
In: Chemistry
You are fractionally distilling 100 mL of a 1:1 solution of cyclohexane and toluene. After 2 mL has distilled you collect a sample for analysis. It is determined that your sample contains a mixture that is 92:8 cyclohexane/toluene. Calculate the number of theoretical plates if the relative volatility (?) of the original solution is 2.33
In: Chemistry
Write a balanced reaction that describes the conversion of Spessartine (Mn3Al2Si3O12) to Tephroite (Mn2SiO4), Kyanite (Al2SiO5), and Quartz (SiO2)
Please show work and explain.
In: Chemistry
Please show the mechanism of RCHO or a ketone reacting with a nucleophile.
In: Chemistry
A compound dissolved in methanol and need to remove by distillation because heat is sensitive, a person hesitate to rait temp above 0C and instead decide to use vacuum distillaion. What required pressure for pure methanol to boil at this temp?
In: Chemistry