draw out the mechanism for synthesis Butyl acetate including a
transition state
draw out the mechanism for synthesis Butyl acetate including a
transition state
Solutions
Expert Solution
n-Butyl acetate, also known as butyl ethanoate, is an organic
compound commonly used as a solvent in the production of lacquers
and other products.
Butyl acetate is found in many types of fruit, where along with
other chemicals it imparts characteristic flavors.
Apples, especially of the Red Delicious variety, are flavored
in part by this chemical.
n-Butyl acetate has three isomers: isobutyl acetate, tert-butyl
acetate, and sec-butyl acetate.
Esters can be prepared by the reaction of a carboxylic acid
with an alcohol in the presence of a catalyst such as concentrated
sulfuric acid, hydrogen chloride, p-toluenesulfonic acid, or the
acid form of an ion exchange resin.
n-Butyl acetate, sec-butyl acetate, tert-butyl acetate, and
isobutyl acetate were previously collected on charcoal tubes and
analyzed by Organic Vapors.
n-butyl acetate by refluxing the n-butyl alcohol with an excess
of acetic acid and a small amount of sulfuric acid as a
catalyst.
The excess acetic acid and unreacted alcohol are separated from
the product by extracting them with water using a separatory
funnel.
A colourless flammable liquid with a fruity odour, butyl
acetate is produced by the esterification of acetic acid using
butanol in the presence of a catalyst such as sulphuric acid.
It is also used as a synthetic fruit flavoring in foods such as
candy, ice cream, cheeses, and baked goods.
In recent years, the Butyl Acetate has seen rising demand for
uses as an oxygenated solvent substitute for hazardous air
pollutants , such as aromatics and ketones
Figure out the RI mixture mole fraction of ethyl acetate and butyl acetate with these numbers: A- Pure ethyl acetate: 1.3715 B-Pure butyl acetate: 1.3945 Fraction 1: 1.3715 Fraction 2: 1.384 and fraction 3: 1.395 all at a temperature of 20 degrees.
the formula is: RI mixture= Xa (RI pure A) + Xb (RI pure B).
What is the bonding functional group and elution order of the
following: propyl acetate, butyl acetate, methanol, ethanol,
2-butanone, and 4-methyl-2-pentatnone
Explain what is the difference between the experiments synthesis
of tert-butyl chloride and the synthesis of butyl chloride in terms
of: 1) Process, 2). Reaction mechanism
1. draw a mechanism for the conversion of methoxybenzyl alcohol
to methoxybenzaldehyde.
2.The ethyl acetate layer was extracted with 0.2M NaOH to remove
traces of methoxybenzoic acid that result from additional oxidation
of the aldehyde to the carboxylic acid. Explain how crystals of methoxybenzoic acid
could be isolated from the NaOH solution.
3. Explain how TLC could be used
to monitor the reduction of methoxybenzaldehyde to methoxybenzyl
alcohol using NaBH4 as a reducing agent.
3. BORNEOL OXIDATION: SYNTHESIS OF CAMPHOR
a. Draw a detailed electron pushing mechanism for the reaction
proposed above.
b. In your aqueous extraction (using the separatory funnel),
do you expect the
organic layer to be on top or bottom? What is the crucial
physical property that
you need to know, in order to answer this question?
c. Scenario: you are doing your aqueous wash with (mildly
basic!) NaHCO3 (step
6), and cap the separatory funnel while chatting with your lab...
Lab 8: Synthesis of n-butylbromide
Draw the complete mechanism for the main reaction and indicate
the expected mechanism type. Explain your reasoning.
Discuss the differences of the of n-butyl alcohol and n-butyl
bromide based to their physical properties (think intermolecular
forces), and why they are important to this experiment.
Discuss the general purpose of the initial heating.
Discuss the general purpose of the extraction steps.
Discuss the general purpose of the distillation.