In: Chemistry
Consider the following three-step mechanism for a
reaction:
Br2 (g) ⇌ 2 Br (g) Fast
Br (g) + CHBr3 (g) → HBr (g) + CBr3 (g)
Slow
Br (g) + CBr3 (g) → CBr4 (g) Fast
Based on this mechanism, determine the rate law for the overall reaction.
Rate =
Using the three step mechanism for the given reaction
, the slowest step is the rate determing step for the reaction shown
whereas the fast step are not the rate determining step, so the rate law for the given mechanism can be stated as
Rate = [CHBr3][Br]