Question

In: Chemistry

A Carnot cycle consists of a cycle of 4 processes, in the order: 1) isothermal expansion...

A Carnot cycle consists of a cycle of 4 processes, in the order:

1) isothermal expansion at T(hot)=90oC,

2) adiabatic expansion to T(cold)=30oC,

3) isothermal contraction at T(cold),

4) adiabatic contraction to the original state.

The gas in the system can be treated as a monotonic ideal gas

Part A. After one complete cycle, what is the change in thermal energy of the gas in the system?

Part B. After a complete cycle what is the change in entropy? (The answer to this part is 0 J)

Part C.In this cycle heat can be transferred during which parts of the cycle? (The answer to this part is leg 1 and 3 only)

Part D. What is Q3/Q1, the ratio of heat transferred in leg 3 divided by heat transferred in leg 1 of the cycle?

Part E. What is the Work in terms of Q1 and Q3? (Hint: The work does not depend on Q1 and Q3)

Part F. What is the efficiency of the cycle?

Solutions

Expert Solution

Part A

change in thermal energy is proportional to change in temperature of gas i.e., T2 - T1

But for one complete cycle, starting temperature = end temperature or T1 = T2

Hence T2 - T1 = 0 ; which gives change in thermal energy = 0

Part B

Entropy is a state function and does not depend on path

Let S1 = entropy at start of process, S2 = entropy at end of process

Change in entropy = S2 - S1

But for one complete cycle of carnot cycle, end point is same as start point

Since the state is same, S1 = S2

Hence S1 - S2 = 0 ; which gives change in entropy = 0

Part C

Adiabatic Process means complete insulation of system and no heat nor mass is exchanged between system and surrounding. Hence heat cannot be transferred in 2nd and 4th part of cycle.

In isothermal process, mass cannot be exchanged between system and surrounding but heat flow has no restriction. Hence heat can be transferred during isothermal process i.e., during 1st and 3rd part of cycle.

Part D

Q3/Q1 = -1

This is because Q3 is equal and opposite to Q1

Part E

From 1st law of thermodynamics, Delta U = Q - W

Where Delta U = net change in internal energy, Q = heat energy, W = work done

For isothermal process, Delta U = 0

Hence Q = W ; W1 = Q1 and W3 = Q3

Part F

Efficiency = 1 - (T2 / T1) , where T2 = 30oC and T1 = 90oC

efficiency = 1 - (30oC / 90oC)

efiiciency = 1 - 0.33

efficiency = 0.67


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