In: Chemistry
The photoelectric work function of potassium is 2.3eV. If light with wavelength 250nm falls on potassium find (a) the stopping potential in volts. (b) the kinetic energy in eV of the most energetic electron ejected (c)the speed of these electrons (d)If potassium is replaced with Aluminium, which has a greater work function (4.3eV), compute the change in the threshold frequency.
a)
we know that
KE = hf - W
also
frequency = speed of light (c) / wave length (lamda )
so
KE = hc/lamda - W
now
h = 4.136 x 10-15 eV . s
c = 3 x 10^8 m/s
lamda = 250 x 10-9 m
work function (W) = 2.3 eV
so
KE = ( 4.136 x 10-15 x 3 x 10^8 / 250 x 10-9 ) - 2.3
KE = 2.6632
we know that
kinetic energy KE = eVo
so
eVo = 2.6632 eV
so
Vo = 2.6632
so the stopping potential is 2.6632 Volts
b)
now
K.E max = stopping potenial = 2.6632 eV
c)
now
K.E Max = 2.6632 eV
0.5 mV2 = 2.6632 x 1.6 x 10-19 J
mass of electron = 9.11 x 10-31 kg
so
0.5 x 9.11 x 10-31 x v2 = 2.6632 x 1.6 x 10-19
v2= 9.35 x 10^11
v= sqrt ( 9.35 x 10^11)
v =9.67 x 10^5
so
the speed of those electrons is 9.67 x 10^5 m/s
d)
we know that
work function (W) = hfo
fo is threshold frequency
h = 4.136 x 10-15 eV . s
so
for aluminium
4.3 = 4.136 x 10-15 x fo
fo= 1.04 x 10^15 s-1
For potassium
2.3 - 4.136 x 10-15 x fo
fo = 5.56 x 10^14
so the change in treshold frequency = ( 1.04 x 10^15 - 5.56
x 10^14)
change in threshold frequency = 4.84 x 10^14