Question

In: Chemistry

How do you find the rate constant here? trials [I] [H2O2] [H] temp (C) Rate (M/s)...

How do you find the rate constant here?

trials [I] [H2O2] [H] temp (C) Rate (M/s)
1 8.53*10^-3 1.03*10^-1 0.333 21.5 5.33*10^-4
2 8.53*10^-3 1.03*10^-1 0.333 15 4.3*10^-4
3 8.53*10^-3 1.03*10^-1 0.333 42 2.17*10^-3

Solutions

Expert Solution

In chemical kinetics a reaction rate constant, k or , quantifies the rate of a chemical reaction.[1]

For a reaction between reactants A and B to form product C

the reaction rate is often found to have the form:

Here k(T) is the reaction rate constant that depends on temperature. [A] and [B] are the concentrations of substance A in moles per volume of solution assuming the reaction is taking place throughout the volume of the solution. (For a reaction taking place at a boundary one would use instead moles of A or B per unit area).

trials [I] [H2O2] [H] temp (C) Rate (M/s)
1 8.53*10^-3 1.03*10^-1 0.333 21.5 5.33*10^-4
2 8.53*10^-3 1.03*10^-1 0.333 15 4.3*10^-4
3 8.53*10^-3 1.03*10^-1 0.333 42 2.17*10^-3

1.            T is in K

on solving we get k= 6.827*10-3 L2M-1s-1

2.

on puttin values and solving

k = 6.981*10-3 L2M-1s-1

3.

on puttin values and solving

k = 6.383*10-3 L2M-1s-1


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