Question

In: Chemistry

For each of the following precipitation reactions, calculate how many grams of the first reactant are...

For each of the following precipitation reactions, calculate how many grams of the first reactant are necessary to completely react with 17.0 g of the second reactant. Part A 2KI(aq)+Pb(NO3)2(aq)→PbI2(s)+2KNO3(aq) Part B Na2CO3(aq)+CuCl2(aq)→CuCO3(s)+2NaCl(aq) Part C K2SO4(aq)+Sr(NO3)2(aq)→SrSO4(s)+2KNO3(aq)

Solutions

Expert Solution

a)

Molar mass of Pb(NO3)2 = 1*MM(Pb) + 2*MM(N) + 6*MM(O)

= 1*207.2 + 2*14.01 + 6*16.0

= 331.22 g/mol

mass of Pb(NO3)2 = 17 g

mol of Pb(NO3)2 = (mass)/(molar mass)

= 17/331.22

= 0.0513 mol

From balanced chemical reaction, we see that

when 1 mol of Pb(NO3)2 reacts, 2 mol of KI is reacting

mol of KI reacts = (2/1)* moles of Pb(NO3)2

= (2/1)*0.0513

= 0.1027 mol

Molar mass of KI = 1*MM(K) + 1*MM(I)

= 1*39.1 + 1*126.9

= 166 g/mol

mass of KI = number of mol * molar mass

= 0.1027*166

= 17.04 g

Answer: 17.0 g

b)

Molar mass of CuCl2 = 1*MM(Cu) + 2*MM(Cl)

= 1*63.55 + 2*35.45

= 134.45 g/mol

mass of CuCl2 = 17 g

mol of CuCl2 = (mass)/(molar mass)

= 17/134.45

= 0.1264 mol

From balanced chemical reaction, we see that

when 1 mol of CuCl2 reacts, 1 mol of Na2CO3 is reacting

mol of Na2CO3 reacts = moles of CuCl2

= 0.1264 mol

Molar mass of Na2CO3 = 2*MM(Na) + 1*MM(C) + 3*MM(O)

= 2*22.99 + 1*12.01 + 3*16.0

= 105.99 g/mol

mass of Na2CO3 = number of mol * molar mass

= 0.1264*105.99

= 13.4015 g

Answer: 13.4 g

c)

Molar mass of Sr(NO3)2 = 1*MM(Sr) + 2*MM(N) + 6*MM(O)

= 1*87.62 + 2*14.01 + 6*16.0

= 211.64 g/mol

mass of Sr(NO3)2 = 17 g

mol of Sr(NO3)2 = (mass)/(molar mass)

= 17/211.64

= 0.0803 mol

From balanced chemical reaction, we see that

when 1 mol of Sr(NO3)2 reacts, 1 mol of K2SO4 is reacting

mol of K2SO4 reacts = moles of Sr(NO3)2

= 0.0803 mol

Molar mass of K2SO4 = 2*MM(K) + 1*MM(S) + 4*MM(O)

= 2*39.1 + 1*32.07 + 4*16.0

= 174.27 g/mol

mass of K2SO4 = number of mol * molar mass

= 0.0803*174.27

= 14.0 g

Answer: 14.0 g


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