In: Chemistry
Consider a two-dimensional electron gas in a square box of side L, with periodic boundary conditions.
a) Derive the density of states per unit energy, D(ε).
b) Find the Fermi wavevector, kF, and the Fermi energy, εF, in terms of the number of electrons N and the area of the box, A=L2 .
c) Calculate the density of states at the Fermi energy, D(εF), expressed in terms of N and A. Calculate the heat capacity, CV.
A)
B)
C)
The fermi wave factor kF is defined in terms of the Fermi energy EF
EF hcut 2 kf2 /2m
At zero temperature all states are occupied upto the fermi level
by periodic boundary condition
The seperation between states in the reciprocal lattice is 2/Li in each direction of length
the electron concentration is
n2g 1/(2)2 kF2kF2/2
The wave factor kF (2n2)1/2
Energy factor N 1/A