Question

In: Chemistry

Consider a two-dimensional electron gas in a square box of side L, with periodic boundary conditions....

Consider a two-dimensional electron gas in a square box of side L, with periodic boundary conditions.

a) Derive the density of states per unit energy, D(ε).

b) Find the Fermi wavevector, kF, and the Fermi energy, εF, in terms of the number of electrons N and the area of the box, A=L2 .

c) Calculate the density of states at the Fermi energy, D(εF), expressed in terms of N and A. Calculate the heat capacity, CV.

Solutions

Expert Solution

A)

B)

C)

The fermi wave factor kF is defined in terms of the Fermi energy EF

EF hcut 2 kf2 /2m

At zero temperature all states are occupied upto the fermi level

by periodic boundary condition

The seperation between states in the reciprocal lattice is 2/Li in each direction of length

the electron concentration is

n2g 1/(2)2 kF2kF2/2

The wave factor kF (2n2)1/2

Energy factor N 1/A


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