Question

In: Chemistry

Consider a particle of mass m confined to a one-dimensional box of length L and in...

Consider a particle of mass m confined to a one-dimensional box of length L and in a state with normalized wavefunction. For a partide in a box the energy is given by

En = n2h2/8mL2 and, because the potential energy is zero, all of this energy is kinetic. Use this observation and, without evaluating any integrals, explain why < px2>= n2h2/4L2

Solutions

Expert Solution

The detail explaination of the expression of average momentum is shown below. Since the box is one dimensional thus we assume that the particle moves along X -axis only. Inside the box the potential energy is zero and the all energy inside the box is assumed to be kinetic.


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