In: Chemistry
An X-ray photon of wavelength 0.958 nm strikes a surface. The emitted electron has a kinetic energy of 978 eV .
What is the binding energy of the electron in kJ mol−1?
[KE = 12mv2; 1 electron volt (eV) =
1.602×10−19J]
E = hc/
= 0.958nm = 0.958*10^-9m =
h = 6.625*10^-34 Joule-sec
C = 3*10^8 m/sec
Ephoton = 6.625*10^-34*3*10^8/0.958*10^-9 = 2.075*10^-16 J
E electron = 978ev
= 978*1.602*10^-19J
= 1.56*10^-16J
E binding energy = E photon - E electron
= 2.075*10^-16 - 1.56*10^-16
= (2.075-1.56)*10^-16
= 5.15*10^-17 J = 5.15*10^-20Kj
energy converted to KJ to KJ/mole
E binding energy = 5.15*10^-20KJ*6.023*10^23/moles = 3.1*10^4KJ/mole